1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole

The title compound, C(26)H(23)BrN(6), has been synthesized as a potential ligand for the construction of metal–organic frameworks. The three benzimidazolyl groups present three potential coordination nodes. The dihedral angles between the benzimidazole ring systems are 74.03 (10), 66.49 (9) and 74.0...

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Detalles Bibliográficos
Autores principales: Wei, Tai-Bao, Lu, Yan-Yun, Cao, Cheng, Yao, Hong, Zhang, You-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151820/
https://www.ncbi.nlm.nih.gov/pubmed/21837200
http://dx.doi.org/10.1107/S1600536811023464
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author Wei, Tai-Bao
Lu, Yan-Yun
Cao, Cheng
Yao, Hong
Zhang, You-Ming
author_facet Wei, Tai-Bao
Lu, Yan-Yun
Cao, Cheng
Yao, Hong
Zhang, You-Ming
author_sort Wei, Tai-Bao
collection PubMed
description The title compound, C(26)H(23)BrN(6), has been synthesized as a potential ligand for the construction of metal–organic frameworks. The three benzimidazolyl groups present three potential coordination nodes. The dihedral angles between the benzimidazole ring systems are 74.03 (10), 66.49 (9) and 74.09 (9)°. The structure contains large voids, which contain highly disordered solvent mol­ecules that may be CH(3)CH(2)OH. Since the solvent mol­ecules could not be located, the PLATON/SQUEEZE procedure [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used.
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spelling pubmed-31518202011-08-11 1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole Wei, Tai-Bao Lu, Yan-Yun Cao, Cheng Yao, Hong Zhang, You-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(23)BrN(6), has been synthesized as a potential ligand for the construction of metal–organic frameworks. The three benzimidazolyl groups present three potential coordination nodes. The dihedral angles between the benzimidazole ring systems are 74.03 (10), 66.49 (9) and 74.09 (9)°. The structure contains large voids, which contain highly disordered solvent mol­ecules that may be CH(3)CH(2)OH. Since the solvent mol­ecules could not be located, the PLATON/SQUEEZE procedure [Spek (2009 ▶). Acta Cryst. D65, 148–155] was used. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3151820/ /pubmed/21837200 http://dx.doi.org/10.1107/S1600536811023464 Text en © Wei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wei, Tai-Bao
Lu, Yan-Yun
Cao, Cheng
Yao, Hong
Zhang, You-Ming
1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
title 1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
title_full 1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
title_fullStr 1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
title_full_unstemmed 1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
title_short 1-[2,2-Bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
title_sort 1-[2,2-bis(1,3-benzimidazol-1-ylmeth­yl)-3-bromo­prop­yl]-1,3-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151820/
https://www.ncbi.nlm.nih.gov/pubmed/21837200
http://dx.doi.org/10.1107/S1600536811023464
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