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7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde

In the title compound, C(14)H(15)NO(3), all non-H atoms except for those of the methyl and the disordered ethyl groupare approximately co-planar, the largest deviation from the mean plane being 0.0223 (13) Å at the N atom. In the crystal, the packing of mol­ecules through weak inter­molecular C—H⋯O...

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Detalles Bibliográficos
Autores principales: Li, Hong-Da, Yin, Bing-Zhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151821/
https://www.ncbi.nlm.nih.gov/pubmed/21837106
http://dx.doi.org/10.1107/S160053681102294X
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author Li, Hong-Da
Yin, Bing-Zhu
author_facet Li, Hong-Da
Yin, Bing-Zhu
author_sort Li, Hong-Da
collection PubMed
description In the title compound, C(14)H(15)NO(3), all non-H atoms except for those of the methyl and the disordered ethyl groupare approximately co-planar, the largest deviation from the mean plane being 0.0223 (13) Å at the N atom. In the crystal, the packing of mol­ecules through weak inter­molecular C—H⋯O hydrogen-bonding inter­actions leads to the formation of layers parallel to bc plane. Within these layers, there exist slipped π–π stacking inter­actions between symmetry-related fused rings [centroid–centroid distances = 3.527 (3) and 3.554 (3), slippage = 0.988 and 1.011 Å, respectively]. One ethyl group is disordered over two sets of sites with site-occupation factors of 0.54 and 0.46.
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spelling pubmed-31518212011-08-11 7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde Li, Hong-Da Yin, Bing-Zhu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(15)NO(3), all non-H atoms except for those of the methyl and the disordered ethyl groupare approximately co-planar, the largest deviation from the mean plane being 0.0223 (13) Å at the N atom. In the crystal, the packing of mol­ecules through weak inter­molecular C—H⋯O hydrogen-bonding inter­actions leads to the formation of layers parallel to bc plane. Within these layers, there exist slipped π–π stacking inter­actions between symmetry-related fused rings [centroid–centroid distances = 3.527 (3) and 3.554 (3), slippage = 0.988 and 1.011 Å, respectively]. One ethyl group is disordered over two sets of sites with site-occupation factors of 0.54 and 0.46. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151821/ /pubmed/21837106 http://dx.doi.org/10.1107/S160053681102294X Text en © Li and Yin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Hong-Da
Yin, Bing-Zhu
7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde
title 7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde
title_full 7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde
title_fullStr 7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde
title_full_unstemmed 7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde
title_short 7-Diethyl­amino-2-oxo-2H-chromene-3-carbaldehyde
title_sort 7-diethyl­amino-2-oxo-2h-chromene-3-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151821/
https://www.ncbi.nlm.nih.gov/pubmed/21837106
http://dx.doi.org/10.1107/S160053681102294X
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