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7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde
In the title compound, C(14)H(15)NO(3), all non-H atoms except for those of the methyl and the disordered ethyl groupare approximately co-planar, the largest deviation from the mean plane being 0.0223 (13) Å at the N atom. In the crystal, the packing of molecules through weak intermolecular C—H⋯O...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151821/ https://www.ncbi.nlm.nih.gov/pubmed/21837106 http://dx.doi.org/10.1107/S160053681102294X |
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author | Li, Hong-Da Yin, Bing-Zhu |
author_facet | Li, Hong-Da Yin, Bing-Zhu |
author_sort | Li, Hong-Da |
collection | PubMed |
description | In the title compound, C(14)H(15)NO(3), all non-H atoms except for those of the methyl and the disordered ethyl groupare approximately co-planar, the largest deviation from the mean plane being 0.0223 (13) Å at the N atom. In the crystal, the packing of molecules through weak intermolecular C—H⋯O hydrogen-bonding interactions leads to the formation of layers parallel to bc plane. Within these layers, there exist slipped π–π stacking interactions between symmetry-related fused rings [centroid–centroid distances = 3.527 (3) and 3.554 (3), slippage = 0.988 and 1.011 Å, respectively]. One ethyl group is disordered over two sets of sites with site-occupation factors of 0.54 and 0.46. |
format | Online Article Text |
id | pubmed-3151821 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518212011-08-11 7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde Li, Hong-Da Yin, Bing-Zhu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(15)NO(3), all non-H atoms except for those of the methyl and the disordered ethyl groupare approximately co-planar, the largest deviation from the mean plane being 0.0223 (13) Å at the N atom. In the crystal, the packing of molecules through weak intermolecular C—H⋯O hydrogen-bonding interactions leads to the formation of layers parallel to bc plane. Within these layers, there exist slipped π–π stacking interactions between symmetry-related fused rings [centroid–centroid distances = 3.527 (3) and 3.554 (3), slippage = 0.988 and 1.011 Å, respectively]. One ethyl group is disordered over two sets of sites with site-occupation factors of 0.54 and 0.46. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151821/ /pubmed/21837106 http://dx.doi.org/10.1107/S160053681102294X Text en © Li and Yin 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Hong-Da Yin, Bing-Zhu 7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde |
title | 7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde |
title_full | 7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde |
title_fullStr | 7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde |
title_full_unstemmed | 7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde |
title_short | 7-Diethylamino-2-oxo-2H-chromene-3-carbaldehyde |
title_sort | 7-diethylamino-2-oxo-2h-chromene-3-carbaldehyde |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151821/ https://www.ncbi.nlm.nih.gov/pubmed/21837106 http://dx.doi.org/10.1107/S160053681102294X |
work_keys_str_mv | AT lihongda 7diethylamino2oxo2hchromene3carbaldehyde AT yinbingzhu 7diethylamino2oxo2hchromene3carbaldehyde |