Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc

In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia­zole and by two carboxylate O atoms from two 4-nitro­benzoate ligands, adopting a slightly distorted tetra­hedral coordination geometry. I...

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Detalles Bibliográficos
Autores principales: Sun, Xue-Tong, Wang, Xiu-Guang, Zhao, Xiao-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151824/
https://www.ncbi.nlm.nih.gov/pubmed/21836917
http://dx.doi.org/10.1107/S1600536811022331
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author Sun, Xue-Tong
Wang, Xiu-Guang
Zhao, Xiao-Jun
author_facet Sun, Xue-Tong
Wang, Xiu-Guang
Zhao, Xiao-Jun
author_sort Sun, Xue-Tong
collection PubMed
description In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia­zole and by two carboxylate O atoms from two 4-nitro­benzoate ligands, adopting a slightly distorted tetra­hedral coordination geometry. In the crystal, inter­molecular N—H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1,3-benzothia­zole and the carboxyl­ate group of 4-nitro­benzoate link these discrete mononuclear units into a one-dimensional supra­molecular chain extending parallel to [100].
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spelling pubmed-31518242011-08-11 Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc Sun, Xue-Tong Wang, Xiu-Guang Zhao, Xiao-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Zn(C(7)H(4)NO(4))(2)(C(8)H(8)N(2)S)(2)], the Zn(II) atom is coordinated by two N atoms from two 2-amino-6-methyl-1,3-benzothia­zole and by two carboxylate O atoms from two 4-nitro­benzoate ligands, adopting a slightly distorted tetra­hedral coordination geometry. In the crystal, inter­molecular N—H⋯O hydrogen bonds between the amino group of 2-amino-6-methyl-1,3-benzothia­zole and the carboxyl­ate group of 4-nitro­benzoate link these discrete mononuclear units into a one-dimensional supra­molecular chain extending parallel to [100]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151824/ /pubmed/21836917 http://dx.doi.org/10.1107/S1600536811022331 Text en © Sun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Xue-Tong
Wang, Xiu-Guang
Zhao, Xiao-Jun
Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc
title Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc
title_full Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc
title_fullStr Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc
title_full_unstemmed Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc
title_short Bis(2-amino-6-methyl-1,3-benzothia­zole-κN (3))bis­(4-nitro­benzoato-κO (1))zinc
title_sort bis(2-amino-6-methyl-1,3-benzothia­zole-κn (3))bis­(4-nitro­benzoato-κo (1))zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151824/
https://www.ncbi.nlm.nih.gov/pubmed/21836917
http://dx.doi.org/10.1107/S1600536811022331
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