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{N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate
In the title compound, [CuBr(C(17)H(20)N(4))]BF(4), the Cu(II) ion is five-coordinated by the four N atoms of the tetradentate Schiff base ligand and by one bromide ion, thereby forming a square-pyramidal CuN(4)Br coordination geometry. The dihedral angle between the pyridine rings of the Schiff ba...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151825/ https://www.ncbi.nlm.nih.gov/pubmed/21836872 http://dx.doi.org/10.1107/S1600536811022513 |
| _version_ | 1782209664626196480 |
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| author | Liu, Li-Jun |
| author_facet | Liu, Li-Jun |
| author_sort | Liu, Li-Jun |
| collection | PubMed |
| description | In the title compound, [CuBr(C(17)H(20)N(4))]BF(4), the Cu(II) ion is five-coordinated by the four N atoms of the tetradentate Schiff base ligand and by one bromide ion, thereby forming a square-pyramidal CuN(4)Br coordination geometry. The dihedral angle between the pyridine rings of the Schiff base is 54.39 (18)°. In the crystal, the components are linked by C—H⋯F interactions. |
| format | Online Article Text |
| id | pubmed-3151825 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31518252011-08-11 {N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate Liu, Li-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuBr(C(17)H(20)N(4))]BF(4), the Cu(II) ion is five-coordinated by the four N atoms of the tetradentate Schiff base ligand and by one bromide ion, thereby forming a square-pyramidal CuN(4)Br coordination geometry. The dihedral angle between the pyridine rings of the Schiff base is 54.39 (18)°. In the crystal, the components are linked by C—H⋯F interactions. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151825/ /pubmed/21836872 http://dx.doi.org/10.1107/S1600536811022513 Text en © Li-Jun Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Li-Jun {N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate |
| title | {N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate |
| title_full | {N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate |
| title_fullStr | {N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate |
| title_full_unstemmed | {N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate |
| title_short | {N,N′-Bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(II) tetrafluoridoborate |
| title_sort | {n,n′-bis[1-(pyridin-2-yl)ethylidene]propane-1,3-diamine}bromidocopper(ii) tetrafluoridoborate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151825/ https://www.ncbi.nlm.nih.gov/pubmed/21836872 http://dx.doi.org/10.1107/S1600536811022513 |
| work_keys_str_mv | AT liulijun nnbis1pyridin2ylethylidenepropane13diaminebromidocopperiitetrafluoridoborate |