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Diaqua[5,5′-dicarboxy-2,2′-(propane-1,3-diyl)bis(1H-imidazole-4-carboxylato)]nickel(II) dihydrate
In the title complex, [Ni(C(13)H(10)N(4)O(8))(H(2)O)(2)]·2H(2)O, the Ni(2+) cation is six-coordinated by two N atoms and two O atoms from the tetradentate anion in equatorial positions and by two water O atoms in axial positions, leading to a distorted octahedral environment. The central C atom of...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151826/ https://www.ncbi.nlm.nih.gov/pubmed/21836961 http://dx.doi.org/10.1107/S1600536811024391 |
Sumario: | In the title complex, [Ni(C(13)H(10)N(4)O(8))(H(2)O)(2)]·2H(2)O, the Ni(2+) cation is six-coordinated by two N atoms and two O atoms from the tetradentate anion in equatorial positions and by two water O atoms in axial positions, leading to a distorted octahedral environment. The central C atom of the propanediyl unit is disordered over two sites in a 0.531 (6):0.469 (6) ratio. In the crystal, adjacent molecules are linked through O—H⋯O and N—H⋯O hydrogen-bonding interactions into a three-dimensional network. |
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