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Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate

In the title complex, [Ni(C(13)H(10)N(4)O(8))(H(2)O)(2)]·2H(2)O, the Ni(2+) cation is six-coordinated by two N atoms and two O atoms from the tetra­dentate anion in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. The central C atom of...

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Detalles Bibliográficos
Autores principales: Jin, Guang-Hua, Li, Xifeng, Hu, Chunyue, Hu, Lixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151826/
https://www.ncbi.nlm.nih.gov/pubmed/21836961
http://dx.doi.org/10.1107/S1600536811024391
Descripción
Sumario:In the title complex, [Ni(C(13)H(10)N(4)O(8))(H(2)O)(2)]·2H(2)O, the Ni(2+) cation is six-coordinated by two N atoms and two O atoms from the tetra­dentate anion in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. The central C atom of the propanediyl unit is disordered over two sites in a 0.531 (6):0.469 (6) ratio. In the crystal, adjacent mol­ecules are linked through O—H⋯O and N—H⋯O hydrogen-bonding inter­actions into a three-dimensional network.