Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate

In the title complex, [Ni(C(13)H(10)N(4)O(8))(H(2)O)(2)]·2H(2)O, the Ni(2+) cation is six-coordinated by two N atoms and two O atoms from the tetra­dentate anion in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. The central C atom of...

Descripción completa

Detalles Bibliográficos
Autores principales: Jin, Guang-Hua, Li, Xifeng, Hu, Chunyue, Hu, Lixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151826/
https://www.ncbi.nlm.nih.gov/pubmed/21836961
http://dx.doi.org/10.1107/S1600536811024391
_version_ 1782209664841154560
author Jin, Guang-Hua
Li, Xifeng
Hu, Chunyue
Hu, Lixin
author_facet Jin, Guang-Hua
Li, Xifeng
Hu, Chunyue
Hu, Lixin
author_sort Jin, Guang-Hua
collection PubMed
description In the title complex, [Ni(C(13)H(10)N(4)O(8))(H(2)O)(2)]·2H(2)O, the Ni(2+) cation is six-coordinated by two N atoms and two O atoms from the tetra­dentate anion in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. The central C atom of the propanediyl unit is disordered over two sites in a 0.531 (6):0.469 (6) ratio. In the crystal, adjacent mol­ecules are linked through O—H⋯O and N—H⋯O hydrogen-bonding inter­actions into a three-dimensional network.
format Online
Article
Text
id pubmed-3151826
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31518262011-08-11 Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate Jin, Guang-Hua Li, Xifeng Hu, Chunyue Hu, Lixin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(13)H(10)N(4)O(8))(H(2)O)(2)]·2H(2)O, the Ni(2+) cation is six-coordinated by two N atoms and two O atoms from the tetra­dentate anion in equatorial positions and by two water O atoms in axial positions, leading to a distorted octa­hedral environment. The central C atom of the propanediyl unit is disordered over two sites in a 0.531 (6):0.469 (6) ratio. In the crystal, adjacent mol­ecules are linked through O—H⋯O and N—H⋯O hydrogen-bonding inter­actions into a three-dimensional network. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151826/ /pubmed/21836961 http://dx.doi.org/10.1107/S1600536811024391 Text en © Jin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jin, Guang-Hua
Li, Xifeng
Hu, Chunyue
Hu, Lixin
Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate
title Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate
title_full Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate
title_fullStr Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate
title_full_unstemmed Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate
title_short Diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1H-imidazole-4-carboxyl­ato)]nickel(II) dihydrate
title_sort diaqua­[5,5′-dicarb­oxy-2,2′-(propane-1,3-di­yl)bis­(1h-imidazole-4-carboxyl­ato)]nickel(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151826/
https://www.ncbi.nlm.nih.gov/pubmed/21836961
http://dx.doi.org/10.1107/S1600536811024391
work_keys_str_mv AT jinguanghua diaqua55dicarboxy22propane13diylbis1himidazole4carboxylatonickeliidihydrate
AT lixifeng diaqua55dicarboxy22propane13diylbis1himidazole4carboxylatonickeliidihydrate
AT huchunyue diaqua55dicarboxy22propane13diylbis1himidazole4carboxylatonickeliidihydrate
AT hulixin diaqua55dicarboxy22propane13diylbis1himidazole4carboxylatonickeliidihydrate

Ejemplares similares