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Di-μ-benzoato-κ(3) O,O′:O′;κ(3) O:O,O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium]
The dinuclear title compound, [Cd(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], lies on a crystallographic twofold axis. The Cd(II) ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline....
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151832/ https://www.ncbi.nlm.nih.gov/pubmed/21836904 http://dx.doi.org/10.1107/S1600536811022185 |
| _version_ | 1782209666188574720 |
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| author | Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
| author_facet | Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
| author_sort | Li, Hong-Jin |
| collection | PubMed |
| description | The dinuclear title compound, [Cd(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], lies on a crystallographic twofold axis. The Cd(II) ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands adopt two different coordination modes, acting as bidentate and bridging tridentate ligands. The discrete neutral molecules further extend their structure into a three-dimensional supramolecular framework by intermolecular π–π [interplanar distances of 3.392 (4) Å] and C—H⋯π stacking interactions [H–mean plane = 2.567 (4) and 2.781 (4) Å]. |
| format | Online Article Text |
| id | pubmed-3151832 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31518322011-08-11 Di-μ-benzoato-κ(3) O,O′:O′;κ(3) O:O,O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium] Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Cd(2)(C(7)H(5)O(2))(4)(C(12)H(8)N(2))(2)], lies on a crystallographic twofold axis. The Cd(II) ions are connected by two bridging benzoate anions and each ion is seven-coordinated by five O atoms from three benzoate ligands and by two N atoms from 1,10-phenanthroline. The benzoate ligands adopt two different coordination modes, acting as bidentate and bridging tridentate ligands. The discrete neutral molecules further extend their structure into a three-dimensional supramolecular framework by intermolecular π–π [interplanar distances of 3.392 (4) Å] and C—H⋯π stacking interactions [H–mean plane = 2.567 (4) and 2.781 (4) Å]. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151832/ /pubmed/21836904 http://dx.doi.org/10.1107/S1600536811022185 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Di-μ-benzoato-κ(3) O,O′:O′;κ(3) O:O,O′-bis[(benzoato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium] |
| title | Di-μ-benzoato-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium] |
| title_full | Di-μ-benzoato-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium] |
| title_fullStr | Di-μ-benzoato-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium] |
| title_full_unstemmed | Di-μ-benzoato-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium] |
| title_short | Di-μ-benzoato-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(benzoato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium] |
| title_sort | di-μ-benzoato-κ(3)
o,o′:o′;κ(3)
o:o,o′-bis[(benzoato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)cadmium] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151832/ https://www.ncbi.nlm.nih.gov/pubmed/21836904 http://dx.doi.org/10.1107/S1600536811022185 |
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