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2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione
In the molecular structure of the title compound, C(21)H(15)N(3)O(4), the interplanar angle between the benzoyl units is 89.7 (1)°. The corresponding angles between the phenylhydrazono and the benzoyl groups are 31.4 (3) and 60.8 (2)°, respectively. In the crystal, a strong resonance-assisted int...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151834/ https://www.ncbi.nlm.nih.gov/pubmed/21836996 http://dx.doi.org/10.1107/S1600536811021143 |
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author | Bustos, Carlos Alvarez-Thon, Luis Barría, Daniela Garland, Maria Teresa Sánchez, Christian |
author_facet | Bustos, Carlos Alvarez-Thon, Luis Barría, Daniela Garland, Maria Teresa Sánchez, Christian |
author_sort | Bustos, Carlos |
collection | PubMed |
description | In the molecular structure of the title compound, C(21)H(15)N(3)O(4), the interplanar angle between the benzoyl units is 89.7 (1)°. The corresponding angles between the phenylhydrazono and the benzoyl groups are 31.4 (3) and 60.8 (2)°, respectively. In the crystal, a strong resonance-assisted intramolecular hydrogen bond (N—H⋯O) and a weak intramolecular hydrogen bond (C—H⋯N) strongly affect the observed conformation of the molecule. The crystal packing is determined by a strong intermolecular hydrogen bond (N—H⋯O), giving rise to a helical chain along the a axis. In addition, two weak intermolecular contacts (C—H⋯O) are observed. |
format | Online Article Text |
id | pubmed-3151834 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518342011-08-11 2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione Bustos, Carlos Alvarez-Thon, Luis Barría, Daniela Garland, Maria Teresa Sánchez, Christian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecular structure of the title compound, C(21)H(15)N(3)O(4), the interplanar angle between the benzoyl units is 89.7 (1)°. The corresponding angles between the phenylhydrazono and the benzoyl groups are 31.4 (3) and 60.8 (2)°, respectively. In the crystal, a strong resonance-assisted intramolecular hydrogen bond (N—H⋯O) and a weak intramolecular hydrogen bond (C—H⋯N) strongly affect the observed conformation of the molecule. The crystal packing is determined by a strong intermolecular hydrogen bond (N—H⋯O), giving rise to a helical chain along the a axis. In addition, two weak intermolecular contacts (C—H⋯O) are observed. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151834/ /pubmed/21836996 http://dx.doi.org/10.1107/S1600536811021143 Text en © Bustos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bustos, Carlos Alvarez-Thon, Luis Barría, Daniela Garland, Maria Teresa Sánchez, Christian 2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title | 2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_full | 2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_fullStr | 2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_full_unstemmed | 2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_short | 2-[2-(4-Nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
title_sort | 2-[2-(4-nitrophenyl)hydrazinylidene]-1,3-diphenylpropane-1,3-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151834/ https://www.ncbi.nlm.nih.gov/pubmed/21836996 http://dx.doi.org/10.1107/S1600536811021143 |
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