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2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione

In the mol­ecular structure of the title compound, C(21)H(15)N(3)O(4), the inter­planar angle between the benzoyl units is 89.7 (1)°. The corresponding angles between the phenyl­hydrazono and the benzoyl groups are 31.4 (3) and 60.8 (2)°, respectively. In the crystal, a strong resonance-assisted int...

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Autores principales: Bustos, Carlos, Alvarez-Thon, Luis, Barría, Daniela, Garland, Maria Teresa, Sánchez, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151834/
https://www.ncbi.nlm.nih.gov/pubmed/21836996
http://dx.doi.org/10.1107/S1600536811021143
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author Bustos, Carlos
Alvarez-Thon, Luis
Barría, Daniela
Garland, Maria Teresa
Sánchez, Christian
author_facet Bustos, Carlos
Alvarez-Thon, Luis
Barría, Daniela
Garland, Maria Teresa
Sánchez, Christian
author_sort Bustos, Carlos
collection PubMed
description In the mol­ecular structure of the title compound, C(21)H(15)N(3)O(4), the inter­planar angle between the benzoyl units is 89.7 (1)°. The corresponding angles between the phenyl­hydrazono and the benzoyl groups are 31.4 (3) and 60.8 (2)°, respectively. In the crystal, a strong resonance-assisted intra­molecular hydrogen bond (N—H⋯O) and a weak intra­molecular hydrogen bond (C—H⋯N) strongly affect the observed conformation of the mol­ecule. The crystal packing is determined by a strong inter­molecular hydrogen bond (N—H⋯O), giving rise to a helical chain along the a axis. In addition, two weak inter­molecular contacts (C—H⋯O) are observed.
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spelling pubmed-31518342011-08-11 2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione Bustos, Carlos Alvarez-Thon, Luis Barría, Daniela Garland, Maria Teresa Sánchez, Christian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecular structure of the title compound, C(21)H(15)N(3)O(4), the inter­planar angle between the benzoyl units is 89.7 (1)°. The corresponding angles between the phenyl­hydrazono and the benzoyl groups are 31.4 (3) and 60.8 (2)°, respectively. In the crystal, a strong resonance-assisted intra­molecular hydrogen bond (N—H⋯O) and a weak intra­molecular hydrogen bond (C—H⋯N) strongly affect the observed conformation of the mol­ecule. The crystal packing is determined by a strong inter­molecular hydrogen bond (N—H⋯O), giving rise to a helical chain along the a axis. In addition, two weak inter­molecular contacts (C—H⋯O) are observed. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151834/ /pubmed/21836996 http://dx.doi.org/10.1107/S1600536811021143 Text en © Bustos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bustos, Carlos
Alvarez-Thon, Luis
Barría, Daniela
Garland, Maria Teresa
Sánchez, Christian
2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title 2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_full 2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_fullStr 2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_full_unstemmed 2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_short 2-[2-(4-Nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
title_sort 2-[2-(4-nitro­phen­yl)hydrazinyl­idene]-1,3-diphenyl­propane-1,3-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151834/
https://www.ncbi.nlm.nih.gov/pubmed/21836996
http://dx.doi.org/10.1107/S1600536811021143
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