Bis[4-bromo-2-(ethyl­imino­meth­yl)phenolato-κ(2) N,O]nickel(II)

In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl­imino­meth­yl)phenolate ligands. The complex forms a one-dimen...

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Detalles Bibliográficos
Autores principales: Chen, Fu Li, Zhang, Shu Hua, Guo, Jing Jing, Zhang, Yi Dong, Feng, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151835/
https://www.ncbi.nlm.nih.gov/pubmed/21836857
http://dx.doi.org/10.1107/S1600536811020885
Descripción
Sumario:In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl­imino­meth­yl)phenolate ligands. The complex forms a one-dimensional chain in the crystal structure through short C—H⋯Br contacts (H⋯Br = 3.009 Å).

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