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Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobaltate(II) tetrahydrate
The asymmetric unit of the title complex, (C(4)H(12)N(2))[Co(C(7)H(3)NO(4))(2)]·4H(2)O, consists of one piperazinediium dication, one [Co(py-2,6-dc)(2)](2−) dianion (where py-2,6-dc is pyridine-2,6-dicarboxylate) and four water molecules. The piperazinediium cation adopts a chair conformation and...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151836/ https://www.ncbi.nlm.nih.gov/pubmed/21836959 http://dx.doi.org/10.1107/S1600536811023518 |
| _version_ | 1782209667089301504 |
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| author | Raissi Shabari, Akbar Ghoddoosi, Nazanin Pourayoubi, Mehrdad Moradi, Shahram |
| author_facet | Raissi Shabari, Akbar Ghoddoosi, Nazanin Pourayoubi, Mehrdad Moradi, Shahram |
| author_sort | Raissi Shabari, Akbar |
| collection | PubMed |
| description | The asymmetric unit of the title complex, (C(4)H(12)N(2))[Co(C(7)H(3)NO(4))(2)]·4H(2)O, consists of one piperazinediium dication, one [Co(py-2,6-dc)(2)](2−) dianion (where py-2,6-dc is pyridine-2,6-dicarboxylate) and four water molecules. The piperazinediium cation adopts a chair conformation and the Co(II) ion is six-coordinated in an N(2)O(4) environment, having a distorted octahedral geometry. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the components, forming a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3151836 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31518362011-08-11 Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobaltate(II) tetrahydrate Raissi Shabari, Akbar Ghoddoosi, Nazanin Pourayoubi, Mehrdad Moradi, Shahram Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, (C(4)H(12)N(2))[Co(C(7)H(3)NO(4))(2)]·4H(2)O, consists of one piperazinediium dication, one [Co(py-2,6-dc)(2)](2−) dianion (where py-2,6-dc is pyridine-2,6-dicarboxylate) and four water molecules. The piperazinediium cation adopts a chair conformation and the Co(II) ion is six-coordinated in an N(2)O(4) environment, having a distorted octahedral geometry. In the crystal, intermolecular O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonds link the components, forming a three-dimensional network. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151836/ /pubmed/21836959 http://dx.doi.org/10.1107/S1600536811023518 Text en © Raissi Shabari et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Raissi Shabari, Akbar Ghoddoosi, Nazanin Pourayoubi, Mehrdad Moradi, Shahram Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cobaltate(II) tetrahydrate |
| title | Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) tetrahydrate |
| title_full | Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) tetrahydrate |
| title_fullStr | Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) tetrahydrate |
| title_full_unstemmed | Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) tetrahydrate |
| title_short | Piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cobaltate(II) tetrahydrate |
| title_sort | piperazine-1,4-diium bis(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cobaltate(ii) tetrahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151836/ https://www.ncbi.nlm.nih.gov/pubmed/21836959 http://dx.doi.org/10.1107/S1600536811023518 |
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