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Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]bis(nitrato-κO)cadmium]
A novel metal–organic framework based on 1,3-bis(imidazol-1-ylmethyl)benzene (1,3-bimb), [Cd(NO(3))(2)(C(14)H(14)N(4))(2)](n), has been synthesized hydrothermally. The structure exhibits a two-dimensional metal–organic (4,4)-net composed of Cd(II) atoms and bimb ligands, and such layers are furth...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151839/ https://www.ncbi.nlm.nih.gov/pubmed/21836888 http://dx.doi.org/10.1107/S1600536811021027 |
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author | Hu, Xi-Ying Yang, Guang-Rui Shan, Wen-Wen |
author_facet | Hu, Xi-Ying Yang, Guang-Rui Shan, Wen-Wen |
author_sort | Hu, Xi-Ying |
collection | PubMed |
description | A novel metal–organic framework based on 1,3-bis(imidazol-1-ylmethyl)benzene (1,3-bimb), [Cd(NO(3))(2)(C(14)H(14)N(4))(2)](n), has been synthesized hydrothermally. The structure exhibits a two-dimensional metal–organic (4,4)-net composed of Cd(II) atoms and bimb ligands, and such layers are further joined through interlayer C—H⋯O hydrogen bonds to generate a three-dimensional supramolecular structure. |
format | Online Article Text |
id | pubmed-3151839 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518392011-08-11 Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]bis(nitrato-κO)cadmium] Hu, Xi-Ying Yang, Guang-Rui Shan, Wen-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A novel metal–organic framework based on 1,3-bis(imidazol-1-ylmethyl)benzene (1,3-bimb), [Cd(NO(3))(2)(C(14)H(14)N(4))(2)](n), has been synthesized hydrothermally. The structure exhibits a two-dimensional metal–organic (4,4)-net composed of Cd(II) atoms and bimb ligands, and such layers are further joined through interlayer C—H⋯O hydrogen bonds to generate a three-dimensional supramolecular structure. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151839/ /pubmed/21836888 http://dx.doi.org/10.1107/S1600536811021027 Text en © Hu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hu, Xi-Ying Yang, Guang-Rui Shan, Wen-Wen Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2) N (3):N (3′)]bis(nitrato-κO)cadmium] |
title | Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]bis(nitrato-κO)cadmium] |
title_full | Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]bis(nitrato-κO)cadmium] |
title_fullStr | Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]bis(nitrato-κO)cadmium] |
title_full_unstemmed | Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]bis(nitrato-κO)cadmium] |
title_short | Poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
N
(3):N
(3′)]bis(nitrato-κO)cadmium] |
title_sort | poly[bis[μ-1,3-bis(imidazol-1-ylmethyl)benzene-κ(2)
n
(3):n
(3′)]bis(nitrato-κo)cadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151839/ https://www.ncbi.nlm.nih.gov/pubmed/21836888 http://dx.doi.org/10.1107/S1600536811021027 |
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