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Poly[[hexakis(μ-benzene-1,4-dicarboxylato)octakis(N,N-dimethylacetamide)hexamanganese(II)] monohydrate]
In the title compound, {[Mn(6)(C(8)H(4)O(4))(6)(C(4)H(9)NO)(8)]·H(2)O}(n), two of the Mn atoms are six-coordinated by six O atoms from three benzene-1,4-dicarboxylate (bdc) ligands and two trans DMA (dimethylacetamide) molecules, whereas two other Mn atoms, located on inversion centers, are both...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151841/ https://www.ncbi.nlm.nih.gov/pubmed/21836847 http://dx.doi.org/10.1107/S1600536811020010 |
Sumario: | In the title compound, {[Mn(6)(C(8)H(4)O(4))(6)(C(4)H(9)NO)(8)]·H(2)O}(n), two of the Mn atoms are six-coordinated by six O atoms from three benzene-1,4-dicarboxylate (bdc) ligands and two trans DMA (dimethylacetamide) molecules, whereas two other Mn atoms, located on inversion centers, are both in octahedral coordinations by six bdc O atoms. The discrete trinuclear manganese secondary building units (SBU) of Mn(3)(O(2)CR)(6) ({–Mn—Mn—Mn-}) are linked through bdc ligands, forming a chain, while the discrete trinuclear SBU of {–Mn—Mn—Mn-} are bridged, forming another chain]. The two types of chains are linked through bdc ligands, resulting in the formation of a layer with 3(6) topology. Weak O—H⋯O and O—H⋯N hydrogen-bonding interactions involving the disordered water molecule (half-occupation) extend the two-dimensional layers into a three-dimensional supramolecular framework. |
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