Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)

The asymmetric unit of the title compound, 2C(12)H(8)N(2)·C(8)H(10)O(8)·2H(2)O, contains one 1,10-phenanthroline mol­ecule, one half-mol­ecule of butane-1,2,3,4-tetra­carb­oxy­lic acid (H(4)BTC) and a water mol­ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Int...

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Detalles Bibliográficos
Autor principal: Zhu, Hong-lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151845/
https://www.ncbi.nlm.nih.gov/pubmed/21837032
http://dx.doi.org/10.1107/S1600536811021398
Descripción
Sumario:The asymmetric unit of the title compound, 2C(12)H(8)N(2)·C(8)H(10)O(8)·2H(2)O, contains one 1,10-phenanthroline mol­ecule, one half-mol­ecule of butane-1,2,3,4-tetra­carb­oxy­lic acid (H(4)BTC) and a water mol­ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Inter­molecular O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.672 (2) and 3.708 (2) Å form an extensive three-dimensional network, which consolidates the crystal packing.

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