Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)

The asymmetric unit of the title compound, 2C(12)H(8)N(2)·C(8)H(10)O(8)·2H(2)O, contains one 1,10-phenanthroline mol­ecule, one half-mol­ecule of butane-1,2,3,4-tetra­carb­oxy­lic acid (H(4)BTC) and a water mol­ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Int...

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Detalles Bibliográficos
Autor principal: Zhu, Hong-lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151845/
https://www.ncbi.nlm.nih.gov/pubmed/21837032
http://dx.doi.org/10.1107/S1600536811021398
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author Zhu, Hong-lin
author_facet Zhu, Hong-lin
author_sort Zhu, Hong-lin
collection PubMed
description The asymmetric unit of the title compound, 2C(12)H(8)N(2)·C(8)H(10)O(8)·2H(2)O, contains one 1,10-phenanthroline mol­ecule, one half-mol­ecule of butane-1,2,3,4-tetra­carb­oxy­lic acid (H(4)BTC) and a water mol­ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Inter­molecular O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.672 (2) and 3.708 (2) Å form an extensive three-dimensional network, which consolidates the crystal packing.
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spelling pubmed-31518452011-08-11 Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2) Zhu, Hong-lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, 2C(12)H(8)N(2)·C(8)H(10)O(8)·2H(2)O, contains one 1,10-phenanthroline mol­ecule, one half-mol­ecule of butane-1,2,3,4-tetra­carb­oxy­lic acid (H(4)BTC) and a water mol­ecule, with the complete tetra-acid generated by crystallographic inversion symmetry. Inter­molecular O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distances = 3.672 (2) and 3.708 (2) Å form an extensive three-dimensional network, which consolidates the crystal packing. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151845/ /pubmed/21837032 http://dx.doi.org/10.1107/S1600536811021398 Text en © Hong-lin Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhu, Hong-lin
Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)
title Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)
title_full Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)
title_fullStr Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)
title_full_unstemmed Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)
title_short Butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)
title_sort butane-1,2,3,4-tetra­carb­oxy­lic acid–1,10-phenanthroline–water (1/2/2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151845/
https://www.ncbi.nlm.nih.gov/pubmed/21837032
http://dx.doi.org/10.1107/S1600536811021398
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