(Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide

The title compound, C(16)H(21)NP(+)·I(−), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P—N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor–acceptor N—H⋯I inter­action is observed.

Detalles Bibliográficos
Autores principales: Peulecke, Normen, Peitz, Stephan, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151846/
https://www.ncbi.nlm.nih.gov/pubmed/21837129
http://dx.doi.org/10.1107/S1600536811020332
Descripción
Sumario:The title compound, C(16)H(21)NP(+)·I(−), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P—N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor–acceptor N—H⋯I inter­action is observed.

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