(Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide

The title compound, C(16)H(21)NP(+)·I(−), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P—N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor–acceptor N—H⋯I inter­action is observed.

Detalles Bibliográficos
Autores principales: Peulecke, Normen, Peitz, Stephan, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151846/
https://www.ncbi.nlm.nih.gov/pubmed/21837129
http://dx.doi.org/10.1107/S1600536811020332
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author Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Peulecke, Normen
collection PubMed
description The title compound, C(16)H(21)NP(+)·I(−), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P—N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor–acceptor N—H⋯I inter­action is observed.
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spelling pubmed-31518462011-08-11 (Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide Peulecke, Normen Peitz, Stephan Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(21)NP(+)·I(−), was obtained by the reaction of Ph(2)PN((i)Pr)P(Ph)N((i)Pr)H with MeI involving cleavage of one of the P—N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor–acceptor N—H⋯I inter­action is observed. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151846/ /pubmed/21837129 http://dx.doi.org/10.1107/S1600536811020332 Text en © Peulecke et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Peulecke, Normen
Peitz, Stephan
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
(Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide
title (Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide
title_full (Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide
title_fullStr (Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide
title_full_unstemmed (Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide
title_short (Isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide
title_sort (isopropyl­amino)(meth­yl)diphenyl­phospho­nium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151846/
https://www.ncbi.nlm.nih.gov/pubmed/21837129
http://dx.doi.org/10.1107/S1600536811020332
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AT mullerberndh isopropylaminomethyldiphenylphosphoniumiodide
AT spannenberganke isopropylaminomethyldiphenylphosphoniumiodide
AT rosenthaluwe isopropylaminomethyldiphenylphosphoniumiodide

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