[μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate

The title compound, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(12)N(6))(H(2)O)(2)]·H(2)O, displays a discrete dinuclear structure, in which the central Cu(II) atom is five-coordinated in a distorted square-based pyramidal coordination geometry and the flexible ligand 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Gui-Ying, He, Cui-Hong, Tong-Fei, Liu, Deng, Xiao-Chen, Shi, Xiao-Ge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151849/
https://www.ncbi.nlm.nih.gov/pubmed/21836927
http://dx.doi.org/10.1107/S1600536811022756
Descripción
Sumario:The title compound, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(12)N(6))(H(2)O)(2)]·H(2)O, displays a discrete dinuclear structure, in which the central Cu(II) atom is five-coordinated in a distorted square-based pyramidal coordination geometry and the flexible ligand 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene adopts a bis-monodentate bridging mode linking the Cu(II) atoms. It is further assembled by O—H⋯O hydrogen-bond inter­actions involving both the coordinated and uncoordinated water molecules. The latter exhibits half-occupancy.

Ejemplares similares