[μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate

The title compound, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(12)N(6))(H(2)O)(2)]·H(2)O, displays a discrete dinuclear structure, in which the central Cu(II) atom is five-coordinated in a distorted square-based pyramidal coordination geometry and the flexible ligand 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Gui-Ying, He, Cui-Hong, Tong-Fei, Liu, Deng, Xiao-Chen, Shi, Xiao-Ge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151849/
https://www.ncbi.nlm.nih.gov/pubmed/21836927
http://dx.doi.org/10.1107/S1600536811022756
_version_ 1782209670088228864
author Dong, Gui-Ying
He, Cui-Hong
Tong-Fei, Liu
Deng, Xiao-Chen
Shi, Xiao-Ge
author_facet Dong, Gui-Ying
He, Cui-Hong
Tong-Fei, Liu
Deng, Xiao-Chen
Shi, Xiao-Ge
author_sort Dong, Gui-Ying
collection PubMed
description The title compound, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(12)N(6))(H(2)O)(2)]·H(2)O, displays a discrete dinuclear structure, in which the central Cu(II) atom is five-coordinated in a distorted square-based pyramidal coordination geometry and the flexible ligand 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene adopts a bis-monodentate bridging mode linking the Cu(II) atoms. It is further assembled by O—H⋯O hydrogen-bond inter­actions involving both the coordinated and uncoordinated water molecules. The latter exhibits half-occupancy.
format Online
Article
Text
id pubmed-3151849
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31518492011-08-11 [μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate Dong, Gui-Ying He, Cui-Hong Tong-Fei, Liu Deng, Xiao-Chen Shi, Xiao-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(7)H(3)NO(4))(2)(C(12)H(12)N(6))(H(2)O)(2)]·H(2)O, displays a discrete dinuclear structure, in which the central Cu(II) atom is five-coordinated in a distorted square-based pyramidal coordination geometry and the flexible ligand 1,4-bis­(1,2,4-triazol-1-ylmeth­yl)benzene adopts a bis-monodentate bridging mode linking the Cu(II) atoms. It is further assembled by O—H⋯O hydrogen-bond inter­actions involving both the coordinated and uncoordinated water molecules. The latter exhibits half-occupancy. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151849/ /pubmed/21836927 http://dx.doi.org/10.1107/S1600536811022756 Text en © Dong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Gui-Ying
He, Cui-Hong
Tong-Fei, Liu
Deng, Xiao-Chen
Shi, Xiao-Ge
[μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate
title [μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate
title_full [μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate
title_fullStr [μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate
title_full_unstemmed [μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate
title_short [μ-1,4-Bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(II)] monohydrate
title_sort [μ-1,4-bis(1,2,4-triazol-1-ylmeth­yl)benzene]­bis­[aqua­(pyridine-2,6-dicarboxyl­ato)copper(ii)] monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151849/
https://www.ncbi.nlm.nih.gov/pubmed/21836927
http://dx.doi.org/10.1107/S1600536811022756
work_keys_str_mv AT dongguiying m14bis124triazol1ylmethylbenzenebisaquapyridine26dicarboxylatocopperiimonohydrate
AT hecuihong m14bis124triazol1ylmethylbenzenebisaquapyridine26dicarboxylatocopperiimonohydrate
AT tongfeiliu m14bis124triazol1ylmethylbenzenebisaquapyridine26dicarboxylatocopperiimonohydrate
AT dengxiaochen m14bis124triazol1ylmethylbenzenebisaquapyridine26dicarboxylatocopperiimonohydrate
AT shixiaoge m14bis124triazol1ylmethylbenzenebisaquapyridine26dicarboxylatocopperiimonohydrate

Ejemplares similares