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(2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III)
The title mononuclear cobalt(III) complex, [Co(C(14)H(19)N(2)O(2))(C(8)H(7)O(2))(NCS)], was obtained by the reaction of 2-acetylphenol, 2-(morpholin-4-yl)ethylamine, ammonium thiocyanate and cobalt nitrate in methanol. The Co(III) atom is coordinated by one phenolate O, one imine N, and one amin...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151850/ https://www.ncbi.nlm.nih.gov/pubmed/21836833 http://dx.doi.org/10.1107/S1600536811025116 |
| _version_ | 1782209670312624128 |
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| author | Wang, Chen-Yi |
| author_facet | Wang, Chen-Yi |
| author_sort | Wang, Chen-Yi |
| collection | PubMed |
| description | The title mononuclear cobalt(III) complex, [Co(C(14)H(19)N(2)O(2))(C(8)H(7)O(2))(NCS)], was obtained by the reaction of 2-acetylphenol, 2-(morpholin-4-yl)ethylamine, ammonium thiocyanate and cobalt nitrate in methanol. The Co(III) atom is coordinated by one phenolate O, one imine N, and one amine N atom of the tridentate Schiff base ligand, two O atoms of the 2-acetylphenolate anion and one thiocyanate N atom. This results in a fairly regular fac-CoN(3)O(3) octahedral coordination geometry for the metal ion. The dihedral angle between the two benzene rings is 88.3 (3)°. |
| format | Online Article Text |
| id | pubmed-3151850 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31518502011-08-11 (2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III) Wang, Chen-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear cobalt(III) complex, [Co(C(14)H(19)N(2)O(2))(C(8)H(7)O(2))(NCS)], was obtained by the reaction of 2-acetylphenol, 2-(morpholin-4-yl)ethylamine, ammonium thiocyanate and cobalt nitrate in methanol. The Co(III) atom is coordinated by one phenolate O, one imine N, and one amine N atom of the tridentate Schiff base ligand, two O atoms of the 2-acetylphenolate anion and one thiocyanate N atom. This results in a fairly regular fac-CoN(3)O(3) octahedral coordination geometry for the metal ion. The dihedral angle between the two benzene rings is 88.3 (3)°. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3151850/ /pubmed/21836833 http://dx.doi.org/10.1107/S1600536811025116 Text en © Chen-Yi Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Chen-Yi (2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III) |
| title | (2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III) |
| title_full | (2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III) |
| title_fullStr | (2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III) |
| title_full_unstemmed | (2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III) |
| title_short | (2-Acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κN)cobalt(III) |
| title_sort | (2-acetylphenolato)(2-{1-[2-(morpholin-4-yl)ethylimino]ethyl}phenolato)(thiocyanato-κn)cobalt(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151850/ https://www.ncbi.nlm.nih.gov/pubmed/21836833 http://dx.doi.org/10.1107/S1600536811025116 |
| work_keys_str_mv | AT wangchenyi 2acetylphenolato212morpholin4ylethyliminoethylphenolatothiocyanatokncobaltiii |