[1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II)

In the crystal structure of title compound, [NiCl(2)(C(14)H(32)P(2))], the Ni(II) atom lies on a twofold rotation axis and shows a slightly distorted square-planar coordination geometry, with a dihedral angle of 10.01 (8)° between the cis-Cl—Ni—Cl and cis-P—Ni—P planes. There is no significant inter...

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Detalles Bibliográficos
Autores principales: Castellanos-Blanco, Nahury Y., García, Juventino J., Flores-Alamo, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151871/
https://www.ncbi.nlm.nih.gov/pubmed/21836867
http://dx.doi.org/10.1107/S1600536811021209
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author Castellanos-Blanco, Nahury Y.
García, Juventino J.
Flores-Alamo, Marcos
author_facet Castellanos-Blanco, Nahury Y.
García, Juventino J.
Flores-Alamo, Marcos
author_sort Castellanos-Blanco, Nahury Y.
collection PubMed
description In the crystal structure of title compound, [NiCl(2)(C(14)H(32)P(2))], the Ni(II) atom lies on a twofold rotation axis and shows a slightly distorted square-planar coordination geometry, with a dihedral angle of 10.01 (8)° between the cis-Cl—Ni—Cl and cis-P—Ni—P planes. There is no significant inter­molecular inter­action except very weak C—H⋯Cl inter­actions. The crystal studied was a racemic twin.
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spelling pubmed-31518712011-08-11 [1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II) Castellanos-Blanco, Nahury Y. García, Juventino J. Flores-Alamo, Marcos Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of title compound, [NiCl(2)(C(14)H(32)P(2))], the Ni(II) atom lies on a twofold rotation axis and shows a slightly distorted square-planar coordination geometry, with a dihedral angle of 10.01 (8)° between the cis-Cl—Ni—Cl and cis-P—Ni—P planes. There is no significant inter­molecular inter­action except very weak C—H⋯Cl inter­actions. The crystal studied was a racemic twin. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151871/ /pubmed/21836867 http://dx.doi.org/10.1107/S1600536811021209 Text en © Castellanos-Blanco et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Castellanos-Blanco, Nahury Y.
García, Juventino J.
Flores-Alamo, Marcos
[1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II)
title [1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II)
title_full [1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II)
title_fullStr [1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II)
title_full_unstemmed [1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II)
title_short [1,2-Bis­(diisopropyl­phosphan­yl)ethane-κ(2) P,P′]dichloridonickel(II)
title_sort [1,2-bis­(diisopropyl­phosphan­yl)ethane-κ(2) p,p′]dichloridonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151871/
https://www.ncbi.nlm.nih.gov/pubmed/21836867
http://dx.doi.org/10.1107/S1600536811021209
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