{4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV)

The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(17)H(14)N(2)O(3))], is five-coordinated within a C(2)N(2)O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is inter­mediate between trigonal-bipyramidal and square-pyramidal. In the cr...

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Detalles Bibliográficos
Autores principales: Affan, Md. Abu, Sam, Norrihan B., Ahmad, Fasihuddin B., White, Fraser, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151873/
https://www.ncbi.nlm.nih.gov/pubmed/21836942
http://dx.doi.org/10.1107/S1600536811023506
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author Affan, Md. Abu
Sam, Norrihan B.
Ahmad, Fasihuddin B.
White, Fraser
Tiekink, Edward R. T.
author_facet Affan, Md. Abu
Sam, Norrihan B.
Ahmad, Fasihuddin B.
White, Fraser
Tiekink, Edward R. T.
author_sort Affan, Md. Abu
collection PubMed
description The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(17)H(14)N(2)O(3))], is five-coordinated within a C(2)N(2)O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is inter­mediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra­molecular zigzag chains propagating along the c- axis direction are mediated by O—H⋯O hydrogen bonds, and weak C—H⋯π inter­actions consolidate the packing.
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spelling pubmed-31518732011-08-11 {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV) Affan, Md. Abu Sam, Norrihan B. Ahmad, Fasihuddin B. White, Fraser Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(17)H(14)N(2)O(3))], is five-coordinated within a C(2)N(2)O donor set provided by the N,N,O-tridentate ligand and two methyl groups. The resultant coordination geometry is inter­mediate between trigonal-bipyramidal and square-pyramidal. In the crystal, supra­molecular zigzag chains propagating along the c- axis direction are mediated by O—H⋯O hydrogen bonds, and weak C—H⋯π inter­actions consolidate the packing. International Union of Crystallography 2011-06-22 /pmc/articles/PMC3151873/ /pubmed/21836942 http://dx.doi.org/10.1107/S1600536811023506 Text en © Affan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Affan, Md. Abu
Sam, Norrihan B.
Ahmad, Fasihuddin B.
White, Fraser
Tiekink, Edward R. T.
{4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV)
title {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV)
title_full {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV)
title_fullStr {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV)
title_full_unstemmed {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV)
title_short {4-Hy­droxy-N′-[(2E,3Z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(IV)
title_sort {4-hy­droxy-n′-[(2e,3z)-4-oxido-4-phenyl­but-3-en-2-yl­idene]benzo­hydrazidato}dimethyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151873/
https://www.ncbi.nlm.nih.gov/pubmed/21836942
http://dx.doi.org/10.1107/S1600536811023506
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