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A second monoclinic polymorph of {bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction
The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a polymorph of the previously reported neutral cobalt(II) complex [Stibrany & Potenza (2010 ▶). Acta Cryst. E66, m506–m507], which contains one each of the monoanionic ligands, bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151874/ https://www.ncbi.nlm.nih.gov/pubmed/21836897 http://dx.doi.org/10.1107/S1600536811021994 |
Sumario: | The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a polymorph of the previously reported neutral cobalt(II) complex [Stibrany & Potenza (2010 ▶). Acta Cryst. E66, m506–m507], which contains one each of the monoanionic ligands, bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borate (Bp) and tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borate (Tp). A distorted octahedral coordination geometry of the Co(II) atom results from ligation of an H atom, which is part of an agostic B—H⋯Co interaction [H⋯Co = 2.12 (3) Å], and by five imine N atoms, two from a Bp ligand and three from a Tp ligand. Weak intra- and intermolecular C—F⋯π interactions with F⋯centroid distances ranging from 3.025 (4) to 3.605 (4) Å are observed. |
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