catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)]

In the title coordination polymer, [Ag(2)(C(8)H(5)N(2)O(6))(2)](n), the silver ion is coordinated to three O atoms from three different anions in an approximate T-shape with one bond much longer than the other two. The polyhedral connectivity leads to [100] chains containing alternating centrosymmet...

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Autores principales: Danish, Muhammad, Tahir, M. Nawaz, Ghafoor, Sabiha, Ahmad, Nazir, Nisa, Mehwish
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151878/
https://www.ncbi.nlm.nih.gov/pubmed/21836922
http://dx.doi.org/10.1107/S1600536811022483
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author Danish, Muhammad
Tahir, M. Nawaz
Ghafoor, Sabiha
Ahmad, Nazir
Nisa, Mehwish
author_facet Danish, Muhammad
Tahir, M. Nawaz
Ghafoor, Sabiha
Ahmad, Nazir
Nisa, Mehwish
author_sort Danish, Muhammad
collection PubMed
description In the title coordination polymer, [Ag(2)(C(8)H(5)N(2)O(6))(2)](n), the silver ion is coordinated to three O atoms from three different anions in an approximate T-shape with one bond much longer than the other two. The polyhedral connectivity leads to [100] chains containing alternating centrosymmetric four-rings and eight-rings, with a short d (10)⋯d (10) Ag⋯Ag interaction [2.8846 (4) Å] across the latter. The nitro groups are oriented at dihedral angles of 21.2 (5) and 64.3 (3)° with respect to the aromatic ring of the ligand. A C—H⋯O inter­action occurs in the crystal.
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spelling pubmed-31518782011-08-11 catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)] Danish, Muhammad Tahir, M. Nawaz Ghafoor, Sabiha Ahmad, Nazir Nisa, Mehwish Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Ag(2)(C(8)H(5)N(2)O(6))(2)](n), the silver ion is coordinated to three O atoms from three different anions in an approximate T-shape with one bond much longer than the other two. The polyhedral connectivity leads to [100] chains containing alternating centrosymmetric four-rings and eight-rings, with a short d (10)⋯d (10) Ag⋯Ag interaction [2.8846 (4) Å] across the latter. The nitro groups are oriented at dihedral angles of 21.2 (5) and 64.3 (3)° with respect to the aromatic ring of the ligand. A C—H⋯O inter­action occurs in the crystal. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151878/ /pubmed/21836922 http://dx.doi.org/10.1107/S1600536811022483 Text en © Danish et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Danish, Muhammad
Tahir, M. Nawaz
Ghafoor, Sabiha
Ahmad, Nazir
Nisa, Mehwish
catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)]
title catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)]
title_full catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)]
title_fullStr catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)]
title_full_unstemmed catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)]
title_short catena-Poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(I)]
title_sort catena-poly[bis­(μ(3)-2-methyl-3,5-dinitro­benzoato)disilver(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151878/
https://www.ncbi.nlm.nih.gov/pubmed/21836922
http://dx.doi.org/10.1107/S1600536811022483
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