Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]

The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))](n), comprises an Rb cation and a 3,5-dinitro­benzoate anion. The Rb cation is eight-coordinated by O atoms from five 3,5-dinitro­benzoate anions. On the other hand, each 3,5-dinitro­benzoate anion links five Rb cations with the carbox...

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Detalles Bibliográficos
Autores principales: Miao, Yanqing, Zhang, Xiaoqing, Liu, Chunye
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151889/
https://www.ncbi.nlm.nih.gov/pubmed/21836829
http://dx.doi.org/10.1107/S1600536811023026
Descripción
Sumario:The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))](n), comprises an Rb cation and a 3,5-dinitro­benzoate anion. The Rb cation is eight-coordinated by O atoms from five 3,5-dinitro­benzoate anions. On the other hand, each 3,5-dinitro­benzoate anion links five Rb cations with the carboxyl­ate groups as μ(3)-bridging. The metal atom is firstly linked by the carboxyl­ate groups into a chain along the c-axis direction, which is further linked by bonds between the Rb and nitro O atoms, giving a three-dimensional framework.

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