Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]

The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))](n), comprises an Rb cation and a 3,5-dinitro­benzoate anion. The Rb cation is eight-coordinated by O atoms from five 3,5-dinitro­benzoate anions. On the other hand, each 3,5-dinitro­benzoate anion links five Rb cations with the carbox...

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Detalles Bibliográficos
Autores principales: Miao, Yanqing, Zhang, Xiaoqing, Liu, Chunye
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151889/
https://www.ncbi.nlm.nih.gov/pubmed/21836829
http://dx.doi.org/10.1107/S1600536811023026
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author Miao, Yanqing
Zhang, Xiaoqing
Liu, Chunye
author_facet Miao, Yanqing
Zhang, Xiaoqing
Liu, Chunye
author_sort Miao, Yanqing
collection PubMed
description The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))](n), comprises an Rb cation and a 3,5-dinitro­benzoate anion. The Rb cation is eight-coordinated by O atoms from five 3,5-dinitro­benzoate anions. On the other hand, each 3,5-dinitro­benzoate anion links five Rb cations with the carboxyl­ate groups as μ(3)-bridging. The metal atom is firstly linked by the carboxyl­ate groups into a chain along the c-axis direction, which is further linked by bonds between the Rb and nitro O atoms, giving a three-dimensional framework.
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spelling pubmed-31518892011-08-11 Poly[(μ(5)-3,5-dinitro­benzoato)rubidium] Miao, Yanqing Zhang, Xiaoqing Liu, Chunye Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Rb(C(7)H(3)N(2)O(6))](n), comprises an Rb cation and a 3,5-dinitro­benzoate anion. The Rb cation is eight-coordinated by O atoms from five 3,5-dinitro­benzoate anions. On the other hand, each 3,5-dinitro­benzoate anion links five Rb cations with the carboxyl­ate groups as μ(3)-bridging. The metal atom is firstly linked by the carboxyl­ate groups into a chain along the c-axis direction, which is further linked by bonds between the Rb and nitro O atoms, giving a three-dimensional framework. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3151889/ /pubmed/21836829 http://dx.doi.org/10.1107/S1600536811023026 Text en © Miao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Miao, Yanqing
Zhang, Xiaoqing
Liu, Chunye
Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]
title Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]
title_full Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]
title_fullStr Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]
title_full_unstemmed Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]
title_short Poly[(μ(5)-3,5-dinitro­benzoato)rubidium]
title_sort poly[(μ(5)-3,5-dinitro­benzoato)rubidium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151889/
https://www.ncbi.nlm.nih.gov/pubmed/21836829
http://dx.doi.org/10.1107/S1600536811023026
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