Cargando…
Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate
In the centrosymmetric dinuclear copper(II) title complex, [Cu(2)Br(2)(C(12)H(17)N(2)O)(2)]·H(2)O, each Cu(II) ion is five coordinated in a square-pyramidal geometry by the N,N′,O-tridentate Schiff base, one Br atom and the bridging O atom of the centrosymmetrically related Schiff base. In the cryst...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151890/ https://www.ncbi.nlm.nih.gov/pubmed/21836915 http://dx.doi.org/10.1107/S1600536811022045 |
_version_ | 1782209679550578688 |
---|---|
author | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
author_facet | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
author_sort | Suleiman Gwaram, Nura |
collection | PubMed |
description | In the centrosymmetric dinuclear copper(II) title complex, [Cu(2)Br(2)(C(12)H(17)N(2)O)(2)]·H(2)O, each Cu(II) ion is five coordinated in a square-pyramidal geometry by the N,N′,O-tridentate Schiff base, one Br atom and the bridging O atom of the centrosymmetrically related Schiff base. In the crystal, the water molecules link the complex molecules into infinite chains along the b axis via O—H⋯Br and C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3151890 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518902011-08-11 Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear copper(II) title complex, [Cu(2)Br(2)(C(12)H(17)N(2)O)(2)]·H(2)O, each Cu(II) ion is five coordinated in a square-pyramidal geometry by the N,N′,O-tridentate Schiff base, one Br atom and the bridging O atom of the centrosymmetrically related Schiff base. In the crystal, the water molecules link the complex molecules into infinite chains along the b axis via O—H⋯Br and C—H⋯O hydrogen bonds. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151890/ /pubmed/21836915 http://dx.doi.org/10.1107/S1600536811022045 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate |
title | Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate |
title_full | Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate |
title_fullStr | Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate |
title_full_unstemmed | Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate |
title_short | Bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(II)] monohydrate |
title_sort | bis(μ-2-{1-[2-(dimethylamino)ethylimino]ethyl}phenolato)bis[bromidocopper(ii)] monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151890/ https://www.ncbi.nlm.nih.gov/pubmed/21836915 http://dx.doi.org/10.1107/S1600536811022045 |
work_keys_str_mv | AT suleimangwaramnura bism212dimethylaminoethyliminoethylphenolatobisbromidocopperiimonohydrate AT khaledihamid bism212dimethylaminoethyliminoethylphenolatobisbromidocopperiimonohydrate AT mohdalihapipah bism212dimethylaminoethyliminoethylphenolatobisbromidocopperiimonohydrate |