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Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate(II)
The title salt, (C(6)H(11)N(2))(2)[Cd(C(7)H(3)NO(4))(2)], displays a discrete mononuclear structure, in which the central Cd(II) atom is six-coordinated in a distorted octahedral coordination geometry by two N and four O atoms from two different pyridine-2,6-dicarboxylate anions in an O (2),N,O (6...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151894/ https://www.ncbi.nlm.nih.gov/pubmed/21836832 http://dx.doi.org/10.1107/S1600536811024792 |
| _version_ | 1782209680440819712 |
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| author | Dong, Gui-Ying Liu, Tong-Fei He, Cui-Hong Deng, Xiao-Chen Shi, Xiao-Ge |
| author_facet | Dong, Gui-Ying Liu, Tong-Fei He, Cui-Hong Deng, Xiao-Chen Shi, Xiao-Ge |
| author_sort | Dong, Gui-Ying |
| collection | PubMed |
| description | The title salt, (C(6)H(11)N(2))(2)[Cd(C(7)H(3)NO(4))(2)], displays a discrete mononuclear structure, in which the central Cd(II) atom is six-coordinated in a distorted octahedral coordination geometry by two N and four O atoms from two different pyridine-2,6-dicarboxylate anions in an O (2),N,O (6)-tridentate chelation mode. The crystal packing is stabilized by N—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.576 (5) Å]. |
| format | Online Article Text |
| id | pubmed-3151894 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31518942011-08-11 Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate(II) Dong, Gui-Ying Liu, Tong-Fei He, Cui-Hong Deng, Xiao-Chen Shi, Xiao-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, (C(6)H(11)N(2))(2)[Cd(C(7)H(3)NO(4))(2)], displays a discrete mononuclear structure, in which the central Cd(II) atom is six-coordinated in a distorted octahedral coordination geometry by two N and four O atoms from two different pyridine-2,6-dicarboxylate anions in an O (2),N,O (6)-tridentate chelation mode. The crystal packing is stabilized by N—H⋯O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.576 (5) Å]. International Union of Crystallography 2011-06-30 /pmc/articles/PMC3151894/ /pubmed/21836832 http://dx.doi.org/10.1107/S1600536811024792 Text en © Dong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dong, Gui-Ying Liu, Tong-Fei He, Cui-Hong Deng, Xiao-Chen Shi, Xiao-Ge Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate(II) |
| title | Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) |
| title_full | Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) |
| title_fullStr | Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) |
| title_full_unstemmed | Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) |
| title_short | Bis(2-propyl-1H-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate(II) |
| title_sort | bis(2-propyl-1h-imidazol-3-ium) bis(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cadmate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151894/ https://www.ncbi.nlm.nih.gov/pubmed/21836832 http://dx.doi.org/10.1107/S1600536811024792 |
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