Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)]

In the title salt, [C(6)H(5)N(CH(3))(3)][Sn(2)Br(5)(C(7)H(6)Br)(4)], the Sn(IV) atoms of the dinuclear anion are bridged by a Br atom; the Sn—Br(bridge) bond lengths are 2.9818 (5) and 3.0470 (5) Å. Both Sn atoms show a distorted cis-trigonal–bipyramidal coordination geometry that is distorted towar...

Descripción completa

Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151895/
https://www.ncbi.nlm.nih.gov/pubmed/21836868
http://dx.doi.org/10.1107/S1600536811021295
_version_ 1782209680668360704
author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description In the title salt, [C(6)H(5)N(CH(3))(3)][Sn(2)Br(5)(C(7)H(6)Br)(4)], the Sn(IV) atoms of the dinuclear anion are bridged by a Br atom; the Sn—Br(bridge) bond lengths are 2.9818 (5) and 3.0470 (5) Å. Both Sn atoms show a distorted cis-trigonal–bipyramidal coordination geometry that is distorted towards a square pyramid. In the crystal, weak C—H⋯π inter­actions occur between anions and cations.
format Online
Article
Text
id pubmed-3151895
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31518952011-08-11 Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)] Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [C(6)H(5)N(CH(3))(3)][Sn(2)Br(5)(C(7)H(6)Br)(4)], the Sn(IV) atoms of the dinuclear anion are bridged by a Br atom; the Sn—Br(bridge) bond lengths are 2.9818 (5) and 3.0470 (5) Å. Both Sn atoms show a distorted cis-trigonal–bipyramidal coordination geometry that is distorted towards a square pyramid. In the crystal, weak C—H⋯π inter­actions occur between anions and cations. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151895/ /pubmed/21836868 http://dx.doi.org/10.1107/S1600536811021295 Text en © Keng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)]
title Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)]
title_full Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)]
title_fullStr Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)]
title_full_unstemmed Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)]
title_short Trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(IV)]
title_sort trimethyl­phenyl­ammonium μ-bromido-bis­[dibromidobis(4-bromobenzyl)stannate(iv)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151895/
https://www.ncbi.nlm.nih.gov/pubmed/21836868
http://dx.doi.org/10.1107/S1600536811021295
work_keys_str_mv AT kengthychun trimethylphenylammoniummbromidobisdibromidobis4bromobenzylstannateiv
AT lokongmun trimethylphenylammoniummbromidobisdibromidobis4bromobenzylstannateiv
AT ngseikweng trimethylphenylammoniummbromidobisdibromidobis4bromobenzylstannateiv

Ejemplares similares