Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II)

The title compound, (C(5)H(14)N(2))[CuBr(4)], was synthesized by hydro­thermal reaction of CuBr(2) with 1-methyl­piperazine in an HBr/water solution. Both amine N atoms are protonated. The Cu—Br distances in the tetrahedral anion are in the range 2.3809 (11)–2.4131 (11) Å. In the crystal, moderately...

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Detalles Bibliográficos
Autor principal: Peng, Cong-hu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151897/
https://www.ncbi.nlm.nih.gov/pubmed/21836944
http://dx.doi.org/10.1107/S1600536811024184
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author Peng, Cong-hu
author_facet Peng, Cong-hu
author_sort Peng, Cong-hu
collection PubMed
description The title compound, (C(5)H(14)N(2))[CuBr(4)], was synthesized by hydro­thermal reaction of CuBr(2) with 1-methyl­piperazine in an HBr/water solution. Both amine N atoms are protonated. The Cu—Br distances in the tetrahedral anion are in the range 2.3809 (11)–2.4131 (11) Å. In the crystal, moderately strong and weak inter­molecular N—H⋯Br hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane.
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spelling pubmed-31518972011-08-11 Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II) Peng, Cong-hu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(5)H(14)N(2))[CuBr(4)], was synthesized by hydro­thermal reaction of CuBr(2) with 1-methyl­piperazine in an HBr/water solution. Both amine N atoms are protonated. The Cu—Br distances in the tetrahedral anion are in the range 2.3809 (11)–2.4131 (11) Å. In the crystal, moderately strong and weak inter­molecular N—H⋯Br hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151897/ /pubmed/21836944 http://dx.doi.org/10.1107/S1600536811024184 Text en © Cong-hu Peng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peng, Cong-hu
Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II)
title Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II)
title_full Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II)
title_fullStr Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II)
title_full_unstemmed Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II)
title_short Bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(II)
title_sort bis(1-methyl­piperazine-1,4-diium) tetra­bromidocuprate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151897/
https://www.ncbi.nlm.nih.gov/pubmed/21836944
http://dx.doi.org/10.1107/S1600536811024184
work_keys_str_mv AT pengconghu bis1methylpiperazine14diiumtetrabromidocuprateii

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