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Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate

In the title compound, C(17)H(15)NO(5)S, the benzene ring of the fused-ring system is twisted by 11.67 (6)° with respect to the thia­zine ring. The atoms of the four-atom methyl ester group and the phenyl ring of the benzyl unit are inclined at 16.50 (7) and 44.52 (3)° with respect to the thia­zine...

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Autores principales: Arshad, Muhammad Nadeem, Khan, Islam Ullah, Zia-ur-Rehman, Muhammad, Shafiq, Muhammad, Asiri, Abdullah M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151898/
https://www.ncbi.nlm.nih.gov/pubmed/21836997
http://dx.doi.org/10.1107/S1600536811020289
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author Arshad, Muhammad Nadeem
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Shafiq, Muhammad
Asiri, Abdullah M.
author_facet Arshad, Muhammad Nadeem
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Shafiq, Muhammad
Asiri, Abdullah M.
author_sort Arshad, Muhammad Nadeem
collection PubMed
description In the title compound, C(17)H(15)NO(5)S, the benzene ring of the fused-ring system is twisted by 11.67 (6)° with respect to the thia­zine ring. The atoms of the four-atom methyl ester group and the phenyl ring of the benzyl unit are inclined at 16.50 (7) and 44.52 (3)° with respect to the thia­zine ring. An intra­molecular O—H⋯O hydrogen bond gives rise to a six-membered S(6) ring motif. In the crystal, mol­ecules are extended through a C—H⋯O inter­action along the a axis. C—H⋯π inter­actions are also observed.
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spelling pubmed-31518982011-08-11 Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate Arshad, Muhammad Nadeem Khan, Islam Ullah Zia-ur-Rehman, Muhammad Shafiq, Muhammad Asiri, Abdullah M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(15)NO(5)S, the benzene ring of the fused-ring system is twisted by 11.67 (6)° with respect to the thia­zine ring. The atoms of the four-atom methyl ester group and the phenyl ring of the benzyl unit are inclined at 16.50 (7) and 44.52 (3)° with respect to the thia­zine ring. An intra­molecular O—H⋯O hydrogen bond gives rise to a six-membered S(6) ring motif. In the crystal, mol­ecules are extended through a C—H⋯O inter­action along the a axis. C—H⋯π inter­actions are also observed. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151898/ /pubmed/21836997 http://dx.doi.org/10.1107/S1600536811020289 Text en © Arshad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Arshad, Muhammad Nadeem
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Shafiq, Muhammad
Asiri, Abdullah M.
Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate
title Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate
title_full Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate
title_fullStr Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate
title_full_unstemmed Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate
title_short Methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate
title_sort methyl 2-benzyl-4-hy­droxy-1,1-dioxo-1,2,3,4-tetra­hydro-1λ(6),2-benzothia­zine-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151898/
https://www.ncbi.nlm.nih.gov/pubmed/21836997
http://dx.doi.org/10.1107/S1600536811020289
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