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Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate
In the title compound, C(17)H(15)NO(5)S, the benzene ring of the fused-ring system is twisted by 11.67 (6)° with respect to the thiazine ring. The atoms of the four-atom methyl ester group and the phenyl ring of the benzyl unit are inclined at 16.50 (7) and 44.52 (3)° with respect to the thiazine...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151898/ https://www.ncbi.nlm.nih.gov/pubmed/21836997 http://dx.doi.org/10.1107/S1600536811020289 |
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author | Arshad, Muhammad Nadeem Khan, Islam Ullah Zia-ur-Rehman, Muhammad Shafiq, Muhammad Asiri, Abdullah M. |
author_facet | Arshad, Muhammad Nadeem Khan, Islam Ullah Zia-ur-Rehman, Muhammad Shafiq, Muhammad Asiri, Abdullah M. |
author_sort | Arshad, Muhammad Nadeem |
collection | PubMed |
description | In the title compound, C(17)H(15)NO(5)S, the benzene ring of the fused-ring system is twisted by 11.67 (6)° with respect to the thiazine ring. The atoms of the four-atom methyl ester group and the phenyl ring of the benzyl unit are inclined at 16.50 (7) and 44.52 (3)° with respect to the thiazine ring. An intramolecular O—H⋯O hydrogen bond gives rise to a six-membered S(6) ring motif. In the crystal, molecules are extended through a C—H⋯O interaction along the a axis. C—H⋯π interactions are also observed. |
format | Online Article Text |
id | pubmed-3151898 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31518982011-08-11 Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate Arshad, Muhammad Nadeem Khan, Islam Ullah Zia-ur-Rehman, Muhammad Shafiq, Muhammad Asiri, Abdullah M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(15)NO(5)S, the benzene ring of the fused-ring system is twisted by 11.67 (6)° with respect to the thiazine ring. The atoms of the four-atom methyl ester group and the phenyl ring of the benzyl unit are inclined at 16.50 (7) and 44.52 (3)° with respect to the thiazine ring. An intramolecular O—H⋯O hydrogen bond gives rise to a six-membered S(6) ring motif. In the crystal, molecules are extended through a C—H⋯O interaction along the a axis. C—H⋯π interactions are also observed. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151898/ /pubmed/21836997 http://dx.doi.org/10.1107/S1600536811020289 Text en © Arshad et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Arshad, Muhammad Nadeem Khan, Islam Ullah Zia-ur-Rehman, Muhammad Shafiq, Muhammad Asiri, Abdullah M. Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate |
title | Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate |
title_full | Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate |
title_fullStr | Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate |
title_full_unstemmed | Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate |
title_short | Methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate |
title_sort | methyl 2-benzyl-4-hydroxy-1,1-dioxo-1,2,3,4-tetrahydro-1λ(6),2-benzothiazine-3-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151898/ https://www.ncbi.nlm.nih.gov/pubmed/21836997 http://dx.doi.org/10.1107/S1600536811020289 |
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