catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]

In the title compound, [Co(2)(C(12)H(8)O(12))(C(12)H(8)N(2))(2)](n), each 3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ate (H(2)chhc(4−)) anion has crystallographically imposed C (2) symmetry and bridges four six-coordinate Co atoms, generating polymeric chains running along [010]. These chain...

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Detalles Bibliográficos
Autor principal: Xu, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151899/
https://www.ncbi.nlm.nih.gov/pubmed/21836841
http://dx.doi.org/10.1107/S1600536811019970
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author Xu, Wei
author_facet Xu, Wei
author_sort Xu, Wei
collection PubMed
description In the title compound, [Co(2)(C(12)H(8)O(12))(C(12)H(8)N(2))(2)](n), each 3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ate (H(2)chhc(4−)) anion has crystallographically imposed C (2) symmetry and bridges four six-coordinate Co atoms, generating polymeric chains running along [010]. These chains are further extended into a three-dimensional network via O—H⋯O hydrogen-bonding inter­actions and inter­chain π–π stacking inter­actions [centroid–centroid distance = 3.662 (2) Å].
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spelling pubmed-31518992011-08-11 catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato] Xu, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(C(12)H(8)O(12))(C(12)H(8)N(2))(2)](n), each 3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ate (H(2)chhc(4−)) anion has crystallographically imposed C (2) symmetry and bridges four six-coordinate Co atoms, generating polymeric chains running along [010]. These chains are further extended into a three-dimensional network via O—H⋯O hydrogen-bonding inter­actions and inter­chain π–π stacking inter­actions [centroid–centroid distance = 3.662 (2) Å]. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151899/ /pubmed/21836841 http://dx.doi.org/10.1107/S1600536811019970 Text en © Wei Xu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Wei
catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]
title catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]
title_full catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]
title_fullStr catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]
title_full_unstemmed catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]
title_short catena-Poly[bis­[(1,10-phenanthroline)cobalt(II)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]
title_sort catena-poly[bis­[(1,10-phenanthroline)cobalt(ii)]-μ(4)-3,6-dicarb­oxy­cyclo­hexane-1,2,4,5-tetra­carboxyl­ato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151899/
https://www.ncbi.nlm.nih.gov/pubmed/21836841
http://dx.doi.org/10.1107/S1600536811019970
work_keys_str_mv AT xuwei catenapolybis110phenanthrolinecobaltiim436dicarboxycyclohexane1245tetracarboxylato

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