tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate

The mol­ecule of the title compound, C(16)H(23)N(3)O(5), is twisted about the chiral C atom, the dihedral angle formed between the amide residues being 79.6 (3)°. The conformation about the imine bond [1.278 (5) Å] is E. In the crystal, O—H⋯O and N—H⋯O hydrogen bonding between the hy­droxy, amine an...

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Autores principales: Pinheiro, Alessandra C., de Souza, Marcus V. N., Tiekink, Edward R. T., Wardell, Solange M. S. V., Wardell, James L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151906/
https://www.ncbi.nlm.nih.gov/pubmed/21837178
http://dx.doi.org/10.1107/S1600536811024263
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author Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
author_facet Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
author_sort Pinheiro, Alessandra C.
collection PubMed
description The mol­ecule of the title compound, C(16)H(23)N(3)O(5), is twisted about the chiral C atom, the dihedral angle formed between the amide residues being 79.6 (3)°. The conformation about the imine bond [1.278 (5) Å] is E. In the crystal, O—H⋯O and N—H⋯O hydrogen bonding between the hy­droxy, amine and carbonyl groups leads to the formation of supra­molecular layers, which stack along the c-axis direction.
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spelling pubmed-31519062011-08-11 tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate Pinheiro, Alessandra C. de Souza, Marcus V. N. Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(16)H(23)N(3)O(5), is twisted about the chiral C atom, the dihedral angle formed between the amide residues being 79.6 (3)°. The conformation about the imine bond [1.278 (5) Å] is E. In the crystal, O—H⋯O and N—H⋯O hydrogen bonding between the hy­droxy, amine and carbonyl groups leads to the formation of supra­molecular layers, which stack along the c-axis direction. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151906/ /pubmed/21837178 http://dx.doi.org/10.1107/S1600536811024263 Text en © Pinheiro et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pinheiro, Alessandra C.
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate
title tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate
title_full tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate
title_fullStr tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate
title_full_unstemmed tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate
title_short tert-Butyl N-((1S)-2-hy­droxy-1-{N′-[(1E)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate
title_sort tert-butyl n-((1s)-2-hy­droxy-1-{n′-[(1e)-4-meth­oxy­benzyl­idene]hydrazinecarbon­yl}eth­yl)carbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151906/
https://www.ncbi.nlm.nih.gov/pubmed/21837178
http://dx.doi.org/10.1107/S1600536811024263
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