Cargando…
Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate dihydrate
The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarboxylic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is pr...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151907/ https://www.ncbi.nlm.nih.gov/pubmed/21836956 http://dx.doi.org/10.1107/S160053681102438X |
Sumario: | The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarboxylic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is propane-1,2-diamine and pydcH(2) is pyridine-2,6-dicarboxylic acid). The Cd(II) ion is coordinated by four O and two N atoms of two pydc ligands in a distorted octahedral environment. The structure also contains two uncoordinated water molecules. In the crystal, there are several intermolecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π stacking interactions between the pyridine rings of pydc units, with centroid–centroid distances of 3.4708 (16) Å. |
---|