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Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate dihydrate
The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarboxylic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is pr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151907/ https://www.ncbi.nlm.nih.gov/pubmed/21836956 http://dx.doi.org/10.1107/S160053681102438X |
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author | Aghabozorg, Hossein Khazaie, Zeynab Agah, Ali Akbar Saemi, Maryam Notash, Behrouz |
author_facet | Aghabozorg, Hossein Khazaie, Zeynab Agah, Ali Akbar Saemi, Maryam Notash, Behrouz |
author_sort | Aghabozorg, Hossein |
collection | PubMed |
description | The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarboxylic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is propane-1,2-diamine and pydcH(2) is pyridine-2,6-dicarboxylic acid). The Cd(II) ion is coordinated by four O and two N atoms of two pydc ligands in a distorted octahedral environment. The structure also contains two uncoordinated water molecules. In the crystal, there are several intermolecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π stacking interactions between the pyridine rings of pydc units, with centroid–centroid distances of 3.4708 (16) Å. |
format | Online Article Text |
id | pubmed-3151907 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519072011-08-11 Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate dihydrate Aghabozorg, Hossein Khazaie, Zeynab Agah, Ali Akbar Saemi, Maryam Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarboxylic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is propane-1,2-diamine and pydcH(2) is pyridine-2,6-dicarboxylic acid). The Cd(II) ion is coordinated by four O and two N atoms of two pydc ligands in a distorted octahedral environment. The structure also contains two uncoordinated water molecules. In the crystal, there are several intermolecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π stacking interactions between the pyridine rings of pydc units, with centroid–centroid distances of 3.4708 (16) Å. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151907/ /pubmed/21836956 http://dx.doi.org/10.1107/S160053681102438X Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Aghabozorg, Hossein Khazaie, Zeynab Agah, Ali Akbar Saemi, Maryam Notash, Behrouz Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cadmate dihydrate |
title | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate dihydrate |
title_full | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate dihydrate |
title_fullStr | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate dihydrate |
title_full_unstemmed | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate dihydrate |
title_short | Propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cadmate dihydrate |
title_sort | propane-1,2-diaminium bis(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cadmate dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151907/ https://www.ncbi.nlm.nih.gov/pubmed/21836956 http://dx.doi.org/10.1107/S160053681102438X |
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