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Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate

The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarb­oxy­lic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is pr...

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Autores principales: Aghabozorg, Hossein, Khazaie, Zeynab, Agah, Ali Akbar, Saemi, Maryam, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151907/
https://www.ncbi.nlm.nih.gov/pubmed/21836956
http://dx.doi.org/10.1107/S160053681102438X
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author Aghabozorg, Hossein
Khazaie, Zeynab
Agah, Ali Akbar
Saemi, Maryam
Notash, Behrouz
author_facet Aghabozorg, Hossein
Khazaie, Zeynab
Agah, Ali Akbar
Saemi, Maryam
Notash, Behrouz
author_sort Aghabozorg, Hossein
collection PubMed
description The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarb­oxy­lic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is propane-1,2-diamine and pydcH(2) is pyridine-2,6-dicarb­oxy­lic acid). The Cd(II) ion is coordinated by four O and two N atoms of two pydc ligands in a distorted octa­hedral environment. The structure also contains two uncoordinated water mol­ecules. In the crystal, there are several inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π stacking inter­actions between the pyridine rings of pydc units, with centroid–centroid distances of 3.4708 (16) Å.
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spelling pubmed-31519072011-08-11 Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate Aghabozorg, Hossein Khazaie, Zeynab Agah, Ali Akbar Saemi, Maryam Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of cadmium nitrate dihydrate, propane-1,2-diamine and pyridine-2,6-dicarb­oxy­lic acid in a 1:1:2 molar ratio in an aqueous solution resulted in the formation of the title compound, (C(3)H(12)N(2))[Cd(C(7)H(3)NO(4))(2)]·2H(2)O or (p-1,2-daH(2))-[Cd(pydc)(2)]·2H(2)O (where p-1,2-da is propane-1,2-diamine and pydcH(2) is pyridine-2,6-dicarb­oxy­lic acid). The Cd(II) ion is coordinated by four O and two N atoms of two pydc ligands in a distorted octa­hedral environment. The structure also contains two uncoordinated water mol­ecules. In the crystal, there are several inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π stacking inter­actions between the pyridine rings of pydc units, with centroid–centroid distances of 3.4708 (16) Å. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151907/ /pubmed/21836956 http://dx.doi.org/10.1107/S160053681102438X Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aghabozorg, Hossein
Khazaie, Zeynab
Agah, Ali Akbar
Saemi, Maryam
Notash, Behrouz
Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate
title Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate
title_full Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate
title_fullStr Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate
title_full_unstemmed Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate
title_short Propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cadmate dihydrate
title_sort propane-1,2-diaminium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))cadmate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151907/
https://www.ncbi.nlm.nih.gov/pubmed/21836956
http://dx.doi.org/10.1107/S160053681102438X
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