[2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II)

The mol­ecule of the title complex, [Ni(C(30)H(23)O(2)P(2))(OH)], adopts a slightly distorted square-planar geometry around Ni(II) defined by the coordination of the two mutually trans P atoms, the Csp (2) atom of the pincer ligand and the O atom of the hydroxide ligand. The largest distortions from...

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Detalles Bibliográficos
Autores principales: Zargarian, Davit, Salah, Abderrahmen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151909/
https://www.ncbi.nlm.nih.gov/pubmed/21836923
http://dx.doi.org/10.1107/S1600536811014267
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author Zargarian, Davit
Salah, Abderrahmen
author_facet Zargarian, Davit
Salah, Abderrahmen
author_sort Zargarian, Davit
collection PubMed
description The mol­ecule of the title complex, [Ni(C(30)H(23)O(2)P(2))(OH)], adopts a slightly distorted square-planar geometry around Ni(II) defined by the coordination of the two mutually trans P atoms, the Csp (2) atom of the pincer ligand and the O atom of the hydroxide ligand. The largest distortions from ideal geometry are reflected in the smaller than usual P—Ni—P [163.95 (3)°] and P—Ni—C [82.06 (6)°] angles. The OH ligand does not form intra- or inter­molecular hydrogen bonds.
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spelling pubmed-31519092011-08-11 [2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II) Zargarian, Davit Salah, Abderrahmen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title complex, [Ni(C(30)H(23)O(2)P(2))(OH)], adopts a slightly distorted square-planar geometry around Ni(II) defined by the coordination of the two mutually trans P atoms, the Csp (2) atom of the pincer ligand and the O atom of the hydroxide ligand. The largest distortions from ideal geometry are reflected in the smaller than usual P—Ni—P [163.95 (3)°] and P—Ni—C [82.06 (6)°] angles. The OH ligand does not form intra- or inter­molecular hydrogen bonds. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151909/ /pubmed/21836923 http://dx.doi.org/10.1107/S1600536811014267 Text en © Zargarian and Salah 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zargarian, Davit
Salah, Abderrahmen
[2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II)
title [2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II)
title_full [2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II)
title_fullStr [2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II)
title_full_unstemmed [2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II)
title_short [2,6-Bis(diphenyl­phosphan­yloxy)phenyl-κ(3) P,C (1),P′]hydroxidonickel(II)
title_sort [2,6-bis(diphenyl­phosphan­yloxy)phenyl-κ(3) p,c (1),p′]hydroxidonickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151909/
https://www.ncbi.nlm.nih.gov/pubmed/21836923
http://dx.doi.org/10.1107/S1600536811014267
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