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{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3) P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate
In the title ionic compound, [Pt(C(17)H(23))(C(34)H(33)P(3))](BF(4))·2CH(2)Cl(2), the Pt(II) atom adopts a square-planar coordination geometry with the large (Z)-8-mesitylcyclooct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to t...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151910/ https://www.ncbi.nlm.nih.gov/pubmed/21836947 http://dx.doi.org/10.1107/S1600536811023853 |
| _version_ | 1782209684047921152 |
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| author | Zhao, Shu-Bin Wang, Rui-Yao Gagné, Michel R. |
| author_facet | Zhao, Shu-Bin Wang, Rui-Yao Gagné, Michel R. |
| author_sort | Zhao, Shu-Bin |
| collection | PubMed |
| description | In the title ionic compound, [Pt(C(17)H(23))(C(34)H(33)P(3))](BF(4))·2CH(2)Cl(2), the Pt(II) atom adopts a square-planar coordination geometry with the large (Z)-8-mesitylcyclooct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclooct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF(4))(−) anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites. |
| format | Online Article Text |
| id | pubmed-3151910 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31519102011-08-11 {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3) P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate Zhao, Shu-Bin Wang, Rui-Yao Gagné, Michel R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title ionic compound, [Pt(C(17)H(23))(C(34)H(33)P(3))](BF(4))·2CH(2)Cl(2), the Pt(II) atom adopts a square-planar coordination geometry with the large (Z)-8-mesitylcyclooct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclooct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF(4))(−) anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151910/ /pubmed/21836947 http://dx.doi.org/10.1107/S1600536811023853 Text en © Zhao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhao, Shu-Bin Wang, Rui-Yao Gagné, Michel R. {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3) P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate |
| title | {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3)
P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate |
| title_full | {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3)
P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate |
| title_fullStr | {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3)
P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate |
| title_full_unstemmed | {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3)
P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate |
| title_short | {Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3)
P,P′,P′′}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate |
| title_sort | {bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-κ(3)
p,p′,p′′}[(z)-8-mesitylcyclooct-4-en-1-yl]platinum(ii) tetrafluoridoborate dichloromethane disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151910/ https://www.ncbi.nlm.nih.gov/pubmed/21836947 http://dx.doi.org/10.1107/S1600536811023853 |
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