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1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)

The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two r...

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Detalles Bibliográficos
Autores principales: Gholizadeh, Mostafa, Maleki, Behrooz, Pourayoubi, Mehrdad, Kia, Mehdi, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151914/
https://www.ncbi.nlm.nih.gov/pubmed/21837022
http://dx.doi.org/10.1107/S1600536811020927
Descripción
Sumario:The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two rings is 3.84 (19)°. In the crystal structure, C—H⋯O hydrogen bonds between the cations and anions lead to the formation of layers arranged parallel to the ab plane. I⋯O halogen bonds [R (2) (2)(4) graph-set motif] range between 2.873 (2) and 3.036 (3) Å and connect neighbouring IO(3) (−) anions with each other along [100], so as to create a three-dimensional network.