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1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)

The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two r...

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Autores principales: Gholizadeh, Mostafa, Maleki, Behrooz, Pourayoubi, Mehrdad, Kia, Mehdi, Notash, Behrouz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151914/
https://www.ncbi.nlm.nih.gov/pubmed/21837022
http://dx.doi.org/10.1107/S1600536811020927
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author Gholizadeh, Mostafa
Maleki, Behrooz
Pourayoubi, Mehrdad
Kia, Mehdi
Notash, Behrouz
author_facet Gholizadeh, Mostafa
Maleki, Behrooz
Pourayoubi, Mehrdad
Kia, Mehdi
Notash, Behrouz
author_sort Gholizadeh, Mostafa
collection PubMed
description The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two rings is 3.84 (19)°. In the crystal structure, C—H⋯O hydrogen bonds between the cations and anions lead to the formation of layers arranged parallel to the ab plane. I⋯O halogen bonds [R (2) (2)(4) graph-set motif] range between 2.873 (2) and 3.036 (3) Å and connect neighbouring IO(3) (−) anions with each other along [100], so as to create a three-dimensional network.
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spelling pubmed-31519142011-08-11 1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate) Gholizadeh, Mostafa Maleki, Behrooz Pourayoubi, Mehrdad Kia, Mehdi Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two rings is 3.84 (19)°. In the crystal structure, C—H⋯O hydrogen bonds between the cations and anions lead to the formation of layers arranged parallel to the ab plane. I⋯O halogen bonds [R (2) (2)(4) graph-set motif] range between 2.873 (2) and 3.036 (3) Å and connect neighbouring IO(3) (−) anions with each other along [100], so as to create a three-dimensional network. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151914/ /pubmed/21837022 http://dx.doi.org/10.1107/S1600536811020927 Text en © Gholizadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gholizadeh, Mostafa
Maleki, Behrooz
Pourayoubi, Mehrdad
Kia, Mehdi
Notash, Behrouz
1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)
title 1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)
title_full 1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)
title_fullStr 1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)
title_full_unstemmed 1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)
title_short 1,1′-(Ethane-1,2-di­yl)dipyridinium bis­(iodate)
title_sort 1,1′-(ethane-1,2-di­yl)dipyridinium bis­(iodate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151914/
https://www.ncbi.nlm.nih.gov/pubmed/21837022
http://dx.doi.org/10.1107/S1600536811020927
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