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1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate)
The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two r...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151914/ https://www.ncbi.nlm.nih.gov/pubmed/21837022 http://dx.doi.org/10.1107/S1600536811020927 |
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author | Gholizadeh, Mostafa Maleki, Behrooz Pourayoubi, Mehrdad Kia, Mehdi Notash, Behrouz |
author_facet | Gholizadeh, Mostafa Maleki, Behrooz Pourayoubi, Mehrdad Kia, Mehdi Notash, Behrouz |
author_sort | Gholizadeh, Mostafa |
collection | PubMed |
description | The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two rings is 3.84 (19)°. In the crystal structure, C—H⋯O hydrogen bonds between the cations and anions lead to the formation of layers arranged parallel to the ab plane. I⋯O halogen bonds [R (2) (2)(4) graph-set motif] range between 2.873 (2) and 3.036 (3) Å and connect neighbouring IO(3) (−) anions with each other along [100], so as to create a three-dimensional network. |
format | Online Article Text |
id | pubmed-3151914 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31519142011-08-11 1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate) Gholizadeh, Mostafa Maleki, Behrooz Pourayoubi, Mehrdad Kia, Mehdi Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(12)H(14)N(2) (2+)·2IO(3) (−), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal–pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two rings is 3.84 (19)°. In the crystal structure, C—H⋯O hydrogen bonds between the cations and anions lead to the formation of layers arranged parallel to the ab plane. I⋯O halogen bonds [R (2) (2)(4) graph-set motif] range between 2.873 (2) and 3.036 (3) Å and connect neighbouring IO(3) (−) anions with each other along [100], so as to create a three-dimensional network. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151914/ /pubmed/21837022 http://dx.doi.org/10.1107/S1600536811020927 Text en © Gholizadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gholizadeh, Mostafa Maleki, Behrooz Pourayoubi, Mehrdad Kia, Mehdi Notash, Behrouz 1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate) |
title | 1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate) |
title_full | 1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate) |
title_fullStr | 1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate) |
title_full_unstemmed | 1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate) |
title_short | 1,1′-(Ethane-1,2-diyl)dipyridinium bis(iodate) |
title_sort | 1,1′-(ethane-1,2-diyl)dipyridinium bis(iodate) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151914/ https://www.ncbi.nlm.nih.gov/pubmed/21837022 http://dx.doi.org/10.1107/S1600536811020927 |
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