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Potassium N,2-dichlorobenzenesulfonamidate sesquihydrate
In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one water molecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water molecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzenesulfonamide anions. The S—N distance o...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151921/ https://www.ncbi.nlm.nih.gov/pubmed/21836899 http://dx.doi.org/10.1107/S1600536811021891 |
Sumario: | In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one water molecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water molecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzenesulfonamide anions. The S—N distance of 1.582 (2) Å is consistent with an S—N double bond. In the structure, the sulfonyl-O and the water-O atoms bridge the K(+) cations in a bidentate fashion. The crystal structure comprises sheets in the ac plane which are further stabilized by intermolecular O—H⋯Cl and O—H⋯N hydrogen bonds. |
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