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Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate

In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one water mol­ecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzene­sulfonamide anions. The S—N distance o...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151921/
https://www.ncbi.nlm.nih.gov/pubmed/21836899
http://dx.doi.org/10.1107/S1600536811021891
Descripción
Sumario:In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one water mol­ecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzene­sulfonamide anions. The S—N distance of 1.582 (2) Å is consistent with an S—N double bond. In the structure, the sulfonyl-O and the water-O atoms bridge the K(+) cations in a bidentate fashion. The crystal structure comprises sheets in the ac plane which are further stabilized by inter­molecular O—H⋯Cl and O—H⋯N hydrogen bonds.