Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate

In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one water mol­ecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzene­sulfonamide anions. The S—N distance o...

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151921/
https://www.ncbi.nlm.nih.gov/pubmed/21836899
http://dx.doi.org/10.1107/S1600536811021891
_version_ 1782209686548774912
author Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_facet Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_sort Gowda, B. Thimme
collection PubMed
description In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one water mol­ecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzene­sulfonamide anions. The S—N distance of 1.582 (2) Å is consistent with an S—N double bond. In the structure, the sulfonyl-O and the water-O atoms bridge the K(+) cations in a bidentate fashion. The crystal structure comprises sheets in the ac plane which are further stabilized by inter­molecular O—H⋯Cl and O—H⋯N hydrogen bonds.
format Online
Article
Text
id pubmed-3151921
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31519212011-08-11 Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate Gowda, B. Thimme Foro, Sabine Shakuntala, K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, K(+)·C(6)H(4)Cl(2)NO(2)S(−)·1.5H(2)O, one water mol­ecule has crystallographically imposed twofold symmetry. The K(+) ion is heptacoordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-chloro-2-chloro-benzene­sulfonamide anions. The S—N distance of 1.582 (2) Å is consistent with an S—N double bond. In the structure, the sulfonyl-O and the water-O atoms bridge the K(+) cations in a bidentate fashion. The crystal structure comprises sheets in the ac plane which are further stabilized by inter­molecular O—H⋯Cl and O—H⋯N hydrogen bonds. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151921/ /pubmed/21836899 http://dx.doi.org/10.1107/S1600536811021891 Text en © Gowda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_full Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_fullStr Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_full_unstemmed Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_short Potassium N,2-dichloro­benzene­sulfonamidate sesquihydrate
title_sort potassium n,2-dichloro­benzene­sulfonamidate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151921/
https://www.ncbi.nlm.nih.gov/pubmed/21836899
http://dx.doi.org/10.1107/S1600536811021891
work_keys_str_mv AT gowdabthimme potassiumn2dichlorobenzenesulfonamidatesesquihydrate
AT forosabine potassiumn2dichlorobenzenesulfonamidatesesquihydrate
AT shakuntalak potassiumn2dichlorobenzenesulfonamidatesesquihydrate

Ejemplares similares