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Potassium N-bromo-2-chlorobenzenesulfonamidate sesquihydrate
In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·1.5H(2)O, the K(+) ion is heptacoordinated by three O atoms from water molecules and by four sulfonyl O atoms of N-bromo-2-chlorobenzenesulfonamidate anions. The S—N distance of 1.582 (4) Å is consistent with an S=N double bond....
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151922/ https://www.ncbi.nlm.nih.gov/pubmed/21836910 http://dx.doi.org/10.1107/S1600536811022136 |
Sumario: | In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·1.5H(2)O, the K(+) ion is heptacoordinated by three O atoms from water molecules and by four sulfonyl O atoms of N-bromo-2-chlorobenzenesulfonamidate anions. The S—N distance of 1.582 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by intermolecular O—H⋯Br and O—H⋯N hydrogen bonds. The asymmetric unit consits of one potassium cation, one N-bromo-2-chlorobenzenesulfonamidate anion and one water molecule in general positions and one water molecule located on a twofold rotation axis. |
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