Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate

In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-chloro­benzene­sulfonamidate anions. The S—N distance of 1.582 (4) Å is consistent with an S=N double bond....

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Shakuntala, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151922/
https://www.ncbi.nlm.nih.gov/pubmed/21836910
http://dx.doi.org/10.1107/S1600536811022136
_version_ 1782209686775267328
author Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_facet Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
author_sort Gowda, B. Thimme
collection PubMed
description In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-chloro­benzene­sulfonamidate anions. The S—N distance of 1.582 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter­molecular O—H⋯Br and O—H⋯N hydrogen bonds. The asymmetric unit consits of one potassium cation, one N-bromo-2-chloro­benzene­sulfonamidate anion and one water mol­ecule in general positions and one water mol­ecule located on a twofold rotation axis.
format Online
Article
Text
id pubmed-3151922
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31519222011-08-11 Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate Gowda, B. Thimme Foro, Sabine Shakuntala, K. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, K(+)·C(6)H(4)BrClNO(2)S(−)·1.5H(2)O, the K(+) ion is hepta­coordinated by three O atoms from water mol­ecules and by four sulfonyl O atoms of N-bromo-2-chloro­benzene­sulfonamidate anions. The S—N distance of 1.582 (4) Å is consistent with an S=N double bond. The crystal structure is stabilized by inter­molecular O—H⋯Br and O—H⋯N hydrogen bonds. The asymmetric unit consits of one potassium cation, one N-bromo-2-chloro­benzene­sulfonamidate anion and one water mol­ecule in general positions and one water mol­ecule located on a twofold rotation axis. International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151922/ /pubmed/21836910 http://dx.doi.org/10.1107/S1600536811022136 Text en © Gowda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gowda, B. Thimme
Foro, Sabine
Shakuntala, K.
Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate
title Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate
title_full Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate
title_fullStr Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate
title_full_unstemmed Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate
title_short Potassium N-bromo-2-chloro­benzene­sulfonamidate sesquihydrate
title_sort potassium n-bromo-2-chloro­benzene­sulfonamidate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151922/
https://www.ncbi.nlm.nih.gov/pubmed/21836910
http://dx.doi.org/10.1107/S1600536811022136
work_keys_str_mv AT gowdabthimme potassiumnbromo2chlorobenzenesulfonamidatesesquihydrate
AT forosabine potassiumnbromo2chlorobenzenesulfonamidatesesquihydrate
AT shakuntalak potassiumnbromo2chlorobenzenesulfonamidatesesquihydrate

Ejemplares similares