Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]

The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)](n), consists of one Zn(2+) cation located on a special position with site symmetry 2/m, one seleno­cyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N a...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Reinert, Thorben, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151927/
https://www.ncbi.nlm.nih.gov/pubmed/21836930
http://dx.doi.org/10.1107/S1600536811023129
Descripción
Sumario:The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)](n), consists of one Zn(2+) cation located on a special position with site symmetry 2/m, one seleno­cyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four pyrimidine ligands and two N-bonded seleno­cyanate anions in mutually trans orientations within a slightly distorted octa­hedral coordination environment. The Zn atoms are μ-1,3-bridged via the pyrimidine ligands into a polymeric layer extending parallel to (100).

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