Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]

The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)](n), consists of one Zn(2+) cation located on a special position with site symmetry 2/m, one seleno­cyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N a...

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Detalles Bibliográficos
Autores principales: Boeckmann, Jan, Reinert, Thorben, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151927/
https://www.ncbi.nlm.nih.gov/pubmed/21836930
http://dx.doi.org/10.1107/S1600536811023129
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author Boeckmann, Jan
Reinert, Thorben
Näther, Christian
author_facet Boeckmann, Jan
Reinert, Thorben
Näther, Christian
author_sort Boeckmann, Jan
collection PubMed
description The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)](n), consists of one Zn(2+) cation located on a special position with site symmetry 2/m, one seleno­cyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four pyrimidine ligands and two N-bonded seleno­cyanate anions in mutually trans orientations within a slightly distorted octa­hedral coordination environment. The Zn atoms are μ-1,3-bridged via the pyrimidine ligands into a polymeric layer extending parallel to (100).
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spelling pubmed-31519272011-08-11 Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc] Boeckmann, Jan Reinert, Thorben Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(NCSe)(2)(C(4)H(4)N(2))(2)](n), consists of one Zn(2+) cation located on a special position with site symmetry 2/m, one seleno­cyanate anion on a mirror plane and one pyrimidine ligand on a twofold rotation axis. The zinc cation is coordinated by six N atoms of four pyrimidine ligands and two N-bonded seleno­cyanate anions in mutually trans orientations within a slightly distorted octa­hedral coordination environment. The Zn atoms are μ-1,3-bridged via the pyrimidine ligands into a polymeric layer extending parallel to (100). International Union of Crystallography 2011-06-18 /pmc/articles/PMC3151927/ /pubmed/21836930 http://dx.doi.org/10.1107/S1600536811023129 Text en © Boeckmann et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boeckmann, Jan
Reinert, Thorben
Näther, Christian
Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]
title Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]
title_full Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]
title_fullStr Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]
title_full_unstemmed Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]
title_short Poly[bis­(μ(2)-pyrimidine-κ(2) N:N′)bis­(seleno­cyanato-κN)zinc]
title_sort poly[bis­(μ(2)-pyrimidine-κ(2) n:n′)bis­(seleno­cyanato-κn)zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151927/
https://www.ncbi.nlm.nih.gov/pubmed/21836930
http://dx.doi.org/10.1107/S1600536811023129
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