Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)]

In the structure of the title compound, [Cu(2)(NO(2))(4)(C(5)H(8)N(2))(4)], the asymmetric unit consists of two moieties containing one Cu ion, two nitrite ions and two 1-ethyl-1H-imidazole mol­ecules associated via weak Cu—O inter­actions. Each Cu(II) atom displays an elongted square-pyramidal CuN(...

Descripción completa

Detalles Bibliográficos
Autor principal: Zhu, Run-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151931/
https://www.ncbi.nlm.nih.gov/pubmed/21836865
http://dx.doi.org/10.1107/S1600536811020745
_version_ 1782209689063260160
author Zhu, Run-Qiang
author_facet Zhu, Run-Qiang
author_sort Zhu, Run-Qiang
collection PubMed
description In the structure of the title compound, [Cu(2)(NO(2))(4)(C(5)H(8)N(2))(4)], the asymmetric unit consists of two moieties containing one Cu ion, two nitrite ions and two 1-ethyl-1H-imidazole mol­ecules associated via weak Cu—O inter­actions. Each Cu(II) atom displays an elongted square-pyramidal CuN(2)O(3) coordination geometry with a slight tetra­hedral distortion in the basal plane. The dimeric units are linked into a three-dimensional network by C—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3151931
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31519312011-08-11 Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)] Zhu, Run-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Cu(2)(NO(2))(4)(C(5)H(8)N(2))(4)], the asymmetric unit consists of two moieties containing one Cu ion, two nitrite ions and two 1-ethyl-1H-imidazole mol­ecules associated via weak Cu—O inter­actions. Each Cu(II) atom displays an elongted square-pyramidal CuN(2)O(3) coordination geometry with a slight tetra­hedral distortion in the basal plane. The dimeric units are linked into a three-dimensional network by C—H⋯O hydrogen bonds. International Union of Crystallography 2011-06-11 /pmc/articles/PMC3151931/ /pubmed/21836865 http://dx.doi.org/10.1107/S1600536811020745 Text en © Run-Qiang Zhu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Run-Qiang
Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)]
title Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)]
title_full Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)]
title_fullStr Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)]
title_full_unstemmed Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)]
title_short Di-μ-nitrito-κ(4) O:O-bis­[bis­(1-ethyl-1H-imidazole-κN (3))(nitrito-κO)copper(II)]
title_sort di-μ-nitrito-κ(4) o:o-bis­[bis­(1-ethyl-1h-imidazole-κn (3))(nitrito-κo)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151931/
https://www.ncbi.nlm.nih.gov/pubmed/21836865
http://dx.doi.org/10.1107/S1600536811020745
work_keys_str_mv AT zhurunqiang dimnitritok4oobisbis1ethyl1himidazolekn3nitritokocopperii

Ejemplares similares