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Aqua­bis­(4-chloro-2-hy­droxy­benzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)

In the title compound, [Zn(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(H(2)O)], the Zn(II) cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water mol­ecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591 (11) Å from the basal plane. The b...

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Detalles Bibliográficos
Autores principales: Nie, Jing-Jing, Xu, Xun, Xu, Duan-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151932/
https://www.ncbi.nlm.nih.gov/pubmed/21836855
http://dx.doi.org/10.1107/S1600536811020435
Descripción
Sumario:In the title compound, [Zn(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(H(2)O)], the Zn(II) cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water mol­ecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591 (11) Å from the basal plane. The benzene rings of the anions are involved in π–π stacking. The centroid–centroid distance between parallel benzene rings of adjacent mol­ecules is 3.9017 (17) Å, and the centroid–centroid distance between benzene and pyridine rings of adjacent mol­ecules is 3.584 (2) Å. Intra­molecular O—H⋯O hydrogen bonding is present.