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Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II)
In the title compound, [Zn(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(H(2)O)], the Zn(II) cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water molecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591 (11) Å from the basal plane. The b...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151932/ https://www.ncbi.nlm.nih.gov/pubmed/21836855 http://dx.doi.org/10.1107/S1600536811020435 |
| _version_ | 1782209689289752576 |
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| author | Nie, Jing-Jing Xu, Xun Xu, Duan-Jun |
| author_facet | Nie, Jing-Jing Xu, Xun Xu, Duan-Jun |
| author_sort | Nie, Jing-Jing |
| collection | PubMed |
| description | In the title compound, [Zn(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(H(2)O)], the Zn(II) cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water molecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591 (11) Å from the basal plane. The benzene rings of the anions are involved in π–π stacking. The centroid–centroid distance between parallel benzene rings of adjacent molecules is 3.9017 (17) Å, and the centroid–centroid distance between benzene and pyridine rings of adjacent molecules is 3.584 (2) Å. Intramolecular O—H⋯O hydrogen bonding is present. |
| format | Online Article Text |
| id | pubmed-3151932 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31519322011-08-11 Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II) Nie, Jing-Jing Xu, Xun Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))(H(2)O)], the Zn(II) cation is coordinated by two 4-chloro-2-salicylate anions, one 1,10-phenanthroline ligand and one water molecule in a square-pyramidal coordination geometry; the Zn cation lies 0.4591 (11) Å from the basal plane. The benzene rings of the anions are involved in π–π stacking. The centroid–centroid distance between parallel benzene rings of adjacent molecules is 3.9017 (17) Å, and the centroid–centroid distance between benzene and pyridine rings of adjacent molecules is 3.584 (2) Å. Intramolecular O—H⋯O hydrogen bonding is present. International Union of Crystallography 2011-06-04 /pmc/articles/PMC3151932/ /pubmed/21836855 http://dx.doi.org/10.1107/S1600536811020435 Text en © Nie et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Nie, Jing-Jing Xu, Xun Xu, Duan-Jun Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2) N,N′)zinc(II) |
| title | Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
| title_full | Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
| title_fullStr | Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
| title_full_unstemmed | Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
| title_short | Aquabis(4-chloro-2-hydroxybenzoato-κO)(1,10-phenanthroline-κ(2)
N,N′)zinc(II) |
| title_sort | aquabis(4-chloro-2-hydroxybenzoato-κo)(1,10-phenanthroline-κ(2)
n,n′)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151932/ https://www.ncbi.nlm.nih.gov/pubmed/21836855 http://dx.doi.org/10.1107/S1600536811020435 |
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