{2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II)

In the title compound, [Co(C(20)H(18)P)I(C(3)H(9)P)(2)], the Co(II) atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe(3) groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby...

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Detalles Bibliográficos
Autores principales: Jia, Jiong, Wang, Chenggen, Liu, Nazhen, Li, Xiaoyan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151933/
https://www.ncbi.nlm.nih.gov/pubmed/21836963
http://dx.doi.org/10.1107/S1600536811022288
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author Jia, Jiong
Wang, Chenggen
Liu, Nazhen
Li, Xiaoyan
author_facet Jia, Jiong
Wang, Chenggen
Liu, Nazhen
Li, Xiaoyan
author_sort Jia, Jiong
collection PubMed
description In the title compound, [Co(C(20)H(18)P)I(C(3)H(9)P)(2)], the Co(II) atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe(3) groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co—C—C—C—P ring.
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spelling pubmed-31519332011-08-11 {2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II) Jia, Jiong Wang, Chenggen Liu, Nazhen Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(20)H(18)P)I(C(3)H(9)P)(2)], the Co(II) atom has a distorted square-pyramidal geometry, the base of which is comprised of two trans PMe(3) groups, an I atom, and a C atom of the benzyl group. This benzyl group is tethered to the P atom at the apex of the pyramid, thereby forming a five-membered chelated Co—C—C—C—P ring. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151933/ /pubmed/21836963 http://dx.doi.org/10.1107/S1600536811022288 Text en © Jia et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jia, Jiong
Wang, Chenggen
Liu, Nazhen
Li, Xiaoyan
{2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II)
title {2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II)
title_full {2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II)
title_fullStr {2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II)
title_full_unstemmed {2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II)
title_short {2-[(Benzylphenyl­phosphanyl-κP)methyl]phenyl-κC (1)}iodidobis(trimethyl­phos­phane)cobalt(II)
title_sort {2-[(benzylphenyl­phosphanyl-κp)methyl]phenyl-κc (1)}iodidobis(trimethyl­phos­phane)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151933/
https://www.ncbi.nlm.nih.gov/pubmed/21836963
http://dx.doi.org/10.1107/S1600536811022288
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