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3,5-Di-O-benzoyl-1,2-O-isopropyl­idene-α-d-ribo-hexos-3-ulo-1,4:3,6-difuran­ose

The title compound, C(23)H(22)O(8), is a binary benzoyl ester whose nucleus consists of a fused system made up of a methyl­enedi­oxy ring and two tetra­hydro­furan rings. One of the benzoyl ester groups is attached at the junction of the two tetra­hydro­furan rings. The other is attached to the oute...

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Detalles Bibliográficos
Autores principales: Zhang, Qiurong, Chen, Xuebin, Zhu, Nan, Jiang, Tengfei, Liu, Hongmin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151936/
https://www.ncbi.nlm.nih.gov/pubmed/21837173
http://dx.doi.org/10.1107/S1600536811024317
Descripción
Sumario:The title compound, C(23)H(22)O(8), is a binary benzoyl ester whose nucleus consists of a fused system made up of a methyl­enedi­oxy ring and two tetra­hydro­furan rings. One of the benzoyl ester groups is attached at the junction of the two tetra­hydro­furan rings. The other is attached to the outer tetra­furan ring. Both the benzoyl ester groups are in an axial conformation with respect to the outer tetrhydro­furan ring. In the crystal, mol­ecules are linked by two weak C—H⋯O hydrogen bonds, forming a chain running parallel to the a axis.