Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)]

In the binuclear centrosymmetric crystal structure of the title compound, [Cu(2)(C(7)H(14)N(5))(2)(C(9)H(21)P)(2)], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal–planar CuN(2)P coordination. Bond angles around the amino N atom...

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Detalles Bibliográficos
Autores principales: Kobrsi, Issam, Bassioni, Ghada
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151938/
https://www.ncbi.nlm.nih.gov/pubmed/21836950
http://dx.doi.org/10.1107/S1600536811022719
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author Kobrsi, Issam
Bassioni, Ghada
author_facet Kobrsi, Issam
Bassioni, Ghada
author_sort Kobrsi, Issam
collection PubMed
description In the binuclear centrosymmetric crystal structure of the title compound, [Cu(2)(C(7)H(14)N(5))(2)(C(9)H(21)P)(2)], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal–planar CuN(2)P coordination. Bond angles around the amino N atom suggest sp (2) hybridization. Several intra­molecular C—H⋯N inter­actions are present involving tetra­zolate N atoms.
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spelling pubmed-31519382011-08-11 Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)] Kobrsi, Issam Bassioni, Ghada Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear centrosymmetric crystal structure of the title compound, [Cu(2)(C(7)H(14)N(5))(2)(C(9)H(21)P)(2)], all atoms except those of the isopropyl groups are approximately co-planar. The Cu(II) atom is in a distorted trigonal–planar CuN(2)P coordination. Bond angles around the amino N atom suggest sp (2) hybridization. Several intra­molecular C—H⋯N inter­actions are present involving tetra­zolate N atoms. International Union of Crystallography 2011-06-25 /pmc/articles/PMC3151938/ /pubmed/21836950 http://dx.doi.org/10.1107/S1600536811022719 Text en © Kobrsi and Bassioni 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kobrsi, Issam
Bassioni, Ghada
Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)]
title Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)]
title_full Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)]
title_fullStr Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)]
title_full_unstemmed Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)]
title_short Bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) N (2):N (3))bis­[(triisopropyl­phosphane)copper(I)]
title_sort bis(μ-5-diisopropyl­amino-1,2,3,4-tetra­zolido-κ(2) n (2):n (3))bis­[(triisopropyl­phosphane)copper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151938/
https://www.ncbi.nlm.nih.gov/pubmed/21836950
http://dx.doi.org/10.1107/S1600536811022719
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